1,2-双[(2S,5S)-2,5-二苯基膦]乙烷(1,5-环辛二烯)四氟硼酸铑(I)

1,2-双[(2S,5S)-2,5-二苯基膦]乙烷(1,5-环辛二烯)四氟硼酸铑(I)，min. 98%

(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 98% (S,S)-Ph-BPE-Rh

货号:J3445-0202

品牌:Strem

纯度:min. 98%

CAS NO:849950-53-4

分子式:[Rh(C?H??)(C??H??P?)]?BF

分子量:804.49

包装	价格
100mg	2228元	留言咨询
500mg	9315元	留言咨询
2g	30156元	留言咨询

仅供研发或工业应用，不可直接用于食品、药品、临床诊断或治疗。

产品介绍

Technical Notes:

1. Phenyl-BPE exhibits enhanced activity and selectivity over existing members of the BPE ligand family in rhodium catalysed asymmetric hydrogenation.

2. This ligand is highly efficient for the hydrogenation of N-acyl aryl-enamides.

3. Molar substrate/catalyst ratios of up to 100,000/1 are achieved with excellent reactivity and enantioselectivity using commercial grade substrates and solvents.

4. Ligand in the rhodium-catalyzed asymmetric hydroformylation of olefins.

References:

1. Org. Lett., 2003, 5, 1273.

2. Tetrahedron Lett, 2004, 45, 9277.

3. Angew. Chem. Int. Ed., 2005, 44, 5834.

应用分类

有机化学 > 催化剂和配体 > 金属催化剂 > 铑催化剂
有机化学 > 不对称合成 > 手性催化剂和配体 > DuPho&BPE 配体

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