(S)-3,3'-二-9-菲基-1,1'-联萘酚膦酸酯

(S)-3,3'-二-9-菲基-1,1'-联萘酚膦酸酯，95%

(11bS)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 95%

货号:J3415-0837

品牌:Strem

纯度:95%

CAS NO:1043567-32-3

分子式:C??H??O?P

分子量:700.71

包装	价格
50mg	5096元	留言咨询

仅供研发或工业应用，不可直接用于食品、药品、临床诊断或治疗。

产品介绍

Technical Notes:

1. Hydrogenation: A catalytic amount of Hantzsch ester that could be regenerated in situ by Ru complexes

under hydrogen gas has been employed in the biomimetic asymmetric hydrogenation of benzoxazinones with up to 99% ee in the presence of chiral phosphoric acid.

2.Friedel-Crafts Reaction: Chiral phosphoric acid-catalyzed enantioselective Friedel-Crafts reaction of indoles with ethyl glyoxylate imines was developed. With 10 mol% of the catalyst.

References: 1. J. Am. Chem. Soc., 2011, 133, 16432-16435. 2. Tetrahedron. L ett., 2009, 65, 1603- 1607.

应用分类

有机化学 > 催化剂和配体 > 配体 > 膦配体 > 其他膦配体
有机化学 > 催化剂和配体 > 有机分子催化剂 > 手性膦酸类有机催化剂

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