Technical Notes:

1.A stable phosphine ligand which can bind to metals such as palladium to be used in Suzuki-Miyaura couplings in making drug intermediates. Dramatic effects in catalysis are also accessible now by using PAd,as a ligand during Suzuki-Miyauracross coupling of chloro(hetero)arenes .

References：

1.Synlett.2017, 2B(3), 280-288.

2. J.Am Chem. 'Soc., '2016 138, 6392.