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CAS: 90076-65-6
分子式: C2HF6NO4S2·Li
分子量: 287.09
熔点: 234-238℃
中文名称: 
1,1,1-三氟-N-[(三氟甲基)磺酰基)甲磺酰胺]锂盐
双(三氟甲基磺酰基)酰亚胺锂
双(三氟甲烷磺酰基)酰亚胺锂
二(三氟甲磺酰)亚胺锂
二-(三氟甲磺酰)亚胺锂
双三氟甲烷磺酰亚胺锂
二-(三氟甲基磺酸酰)亚胺锂
英文名称: 
Methanesulfonamide, 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]-,lithium salt
1,1,1-trifluoro-n-[(trifluoromethyl)sulfonyl]-methanesulfonamidlithium salt
bistrifluoromethanesulfonimide lithium salt
lithium bis(trifluoromethylsulfonyl)imide
Bis(trifluoromethane)sulfonimide lithium salt
Bis(trifluoromethylsulfonyl)amine lithium salt
Lithium Bis(trifluoromethanesulfonyl)imide
Bis(trifluoromethanesulfonyl)imide Lithium Salt
Methanesulfonamide,1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]-,lithium salt
推荐供应商
货号品牌产品名称规格包装、参考价格详情
L708509MACKLIN双三氟甲磺酰亚胺锂电解液1M LiTFSI in Tetraethylene glycol dimethyl ether540元/25ml;   1420元/100ml;   展开
储存：室温,干燥
B822763MACKLIN双三氟甲烷磺酰亚胺锂99.9%48元/1g;   140元/5g;   440元/25g;   916元/100g;   2560元/500g;   8200元/2.5kg;   展开
储存：室温,干燥
状态：白色粉末或晶体
B766362MACKLIN双三氟甲烷磺酰亚胺锂无水级, 99.99% trace metals basis508元/5g;   1525元/25g;   3750元/100g;   11000元/500g;   展开
储存：室温, 干燥
状态：白色粉末或晶体
B802083MACKLIN双三氟甲烷磺酰亚胺锂99%37元/2g;   99元/10g;   295元/50g;   539元/100g;   1120元/250g;   1982元/500g;   7568元/2.5kg;   展开
储存：室温,干燥
状态：白色粉末或晶体
B2542TCILithium Bis(trifluoromethanesulfonyl)imide>98.0%(T)1040元/25G;   4720元/250G;   展开

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量C2F6LiNO4S2 = 287.08
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
Reaxys-RN6625414
PubChem物质ID87557946

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(Ion exchange titration)min. 98.0 %
Melting point231.0 to 237.0 ℃
Water(Vaporization method)max. 1000 ppm

物性(参考值)

熔点235 ℃
水溶性可溶

安全信息

图形或危害标志
信号词危险
危险性说明H301 + H311 : 吞咽或皮肤接触可致中毒。
H314 : 造成严重皮肤灼伤和眼损伤。
H412 : 对水生生物有害并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P260 : 不要吸入粉尘或烟雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P361 + P364 : 立即脱掉所有沾染的衣服，清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽：漱口。不要诱导呕吐。
P301 + P310 + P330 : 如误吞咽：立即呼叫急救中心/医生。漱口。
P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P405 : 存放处须加锁。

运输信息

UN编号UN2923
类别8 / 6.1
包装类别 II
监管条件代码(*)
200644J&KLithium Bis(trifluoromethanesulfonyl)imide98%273元/10G;   1089元/50G;   1858元/250G;   展开

基本信息

分子式C2F6LiNO4S2
分子量287.09
熔点234-238
MDL编码MFCD00210017
Beilstein6625414
EINECS 编号415-300-0

安全信息

图形或危害标志
提示语Danger
危险说明H301
H311
H314
H373
H412
防范说明P273
P280
P301+P310
P305+P351+P338
UN号码2923
危险分类8
次要危险性6.1
包装等级II
WGK3
TSCA是
221472J&KLithium Bis(trifluoromethanesulfonyl)imide99%320元/10G;   1277元/50G;   3901元/250G;   展开

基本信息

分子式C2F6LiNO4S2
分子量287.09
熔点234-238
MDL编码MFCD00210017
Beilstein6625414
EINECS 编号415-300-0

安全信息

图形或危害标志
提示语Danger
危险说明H301
H311
H314
H412
防范说明P273
P280
P301+P310
P305+P351+P338
P310
UN号码2923
危险分类8
次要危险性6.1
包装等级II
WGK2
TSCA是
H27307Alfa AesarLithium bis(trifluoromethylsulfonyl)imide98+%1027元/10g;   3558元/50g;   展开

应用
Lithium bis(trifluoromethylsulfonyl)imide is used in the preparation of chiral imidazolium salt through an anion metathesis of the corresponding triflate organic electrolyte-based lithium batteries. It finds application in the preparation of rare-earth Lewis acid catalysts. It is also useful in primary and secondary lithium cells using organic liquid electrolytes and polymer batteries.

备注
Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00210017

EINECS
415-300-0

分子式
C2F6LiNO4S2

分子量
287.08

熔点
234-238°

灵敏度
Moisture Sensitive. Ambient temperatures.

形态
Powder

溶解性
Soluble in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H311-H314-H373-H412
Toxic if swallowed.Toxic in contact with skin.Causes severe skin burns and eye damage.May cause damage to organs through prolonged or repeated exposure.Harmful to aquatic life with long lasting effects.

Precautionary Statements
P260h-P301+P310a-P303+P361+P353-P305+P351+P338-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
24/25-34-48/22-52/53
Toxic in contact with skin and if swallowed.Causes burns.Harmful: danger of serious damage to health by prolonged exposure if swallowed.Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
22-26-36/37/39-45-61
Do not breathe dust.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid release to the environment. Refer to special instructions/safety data sheets.

TSCA
是

C38103Alfa AesarLithium bis(trifluoromethanesulfonimide)99%1955元/10g;   5761元/50g;   展开

基本信息

Ref#
38103

MDL
210017

分子式
C2 F6 Li N O4 S2

分子量
287.09

形态
White powder

安全信息

危险等级
6.1

包装组
II

15224Sigma-AldrichBis(trifluoromethane)sulfonimide lithium saltpuriss., ≥99.0% (19F-NMR)1163.23元/10 G;   3830.34元/50 G;   展开

产品说明

应用

双(三氟甲烷)磺酰亚胺锂盐(LiTFSI)是锂(Li+)离子的来源，被广泛用作锂离子电池和电容器的有机电解质。LiTFSI还被用作添加剂以增强钙钛矿和染料敏化太阳能电池中的空穴电导率。

包装

10, 50 g in glass bottle

其他说明

适用于锂电池的电解质，使电池表现出很高的导电性

基本信息

线性分子式CF3SO2NLiSO2CF3
分子量287.09
Beilstein6625414
EC 号415-300-0
MDL编号MFCD00210017
PubChem化学物质编号57647343
NACRESNA.22

产品性质

等级puriss.
质量水平100
测定≥99.0% (19F-NMR)
形式powder
杂质≤1% water
mp234-238 ℃ (lit.)
溶解性H2O: 10 mg/mL, clear, colorless
SMILES string[Li]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F
InChI1S/C2F6NO4S2.Li/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1
InChI keyQSZMZKBZAYQGRS-UHFFFAOYSA-N

安全信息

象形图GHS05GHS06GHS08
警示用语：Danger
危险声明H301 + H311 - H314 - H373 - H412
预防措施声明P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Oral
靶器官Nervous system
储存分类代码6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
544094Sigma-AldrichBis(trifluoromethane)sulfonimide lithium salt99.95% trace metals basis630.11元/5 G;   2161.84元/25 G;   6122.07元/100 G;   展开

产品说明

一般描述

双(三氟甲烷)磺酰亚胺锂盐是一种合成试剂。

应用

双(三氟甲烷)磺酰亚胺锂盐可用于以下研究:

  • 作为采用溶液浇铸技术制备凝胶聚合物电解质(GPEs)中的离子液体。
  • 是锂离子电池组成独特的不可燃电解质，具有200℃以上的热稳定性和极高的迁移数。
  • 作为Li-O2 电池的电解质。
  • 是合成锂电池的固体聚合物电解质。

包装

5, 25, 100 g in glass bottle

基本信息

线性分子式CF3SO2NLiSO2CF3
分子量287.09
Beilstein6625414
EC 号415-300-0
MDL编号MFCD00210017
PubChem化学物质编号24878293
NACRESNA.22

产品性质

质量水平100
测定99.95% trace metals basis
mp234-238 ℃ (lit.)
SMILES string[Li]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F
InChI1S/C2F6NO4S2.Li/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1
InChI keyQSZMZKBZAYQGRS-UHFFFAOYSA-N

安全信息

象形图GHS05GHS06GHS08
警示用语：Danger
危险声明H301 + H311 - H314 - H373 - H412
预防措施声明P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Oral
靶器官Nervous system
储存分类代码6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
449504Sigma-AldrichBis(trifluoromethane)sulfonimide lithium salt1165.39元/10 G;   3663.8元/50 G;   15087.2元/250 G;   展开

产品说明

应用

双(三氟甲烷)磺酰亚胺锂盐(Li-TFSI)可用于：

  • 用作提高卟啉基有机太阳能电池电力转换效率的化学添加剂。     
  • 用作制备含咪唑核心单体离子液体的试剂，以开发聚合离子液体。
  • 通过相应三氟甲磺酸酯的阴离子复分解，制备手性咪唑鎓盐。       
  • 合成用于锂离子电池的固体聚合物电解质。 
  • 合成聚电解质可重复使用均相催化剂，可用于异戊二烯和各种亲二烯体间的Diels-Alder反应。
  • 用于制备锂电池电解液和新型稀土路易斯酸催化剂。

包装

10, 50 g in glass bottle

其他说明

关于含氟氮酸的综述，请参见 Coordination Chemistry Reviews。

基本信息

线性分子式CF3SO2NLiSO2CF3
分子量287.09
Beilstein6625414
EC 号415-300-0
MDL编号MFCD00210017
PubChem化学物质编号24868486

产品性质

mp234-238 ℃ (lit.)
SMILES string[Li]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F
InChI1S/C2F6NO4S2.Li/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1
InChI keyQSZMZKBZAYQGRS-UHFFFAOYSA-N

安全信息

象形图GHS05GHS06GHS08
警示用语：Danger
危险声明H301 + H311 - H314 - H373 - H412
预防措施声明P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Oral
靶器官Nervous system
储存分类代码6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
919977Sigma-AldrichLithium Bis(trifluoromethanesulfonyl)imideanhydrous, 99.99% trace metals basis703.32元/10 g;   2327.13元/50 g;   展开

产品说明

应用

LiTFSI has been used as an additive in the synthesis of perovskite solar cells, and a salt for ″Solvent-in-Salt″ electrolytes for lithium ion batteries.

基本信息

线性分子式CF3SO2NLiSO2CF3
分子量287.09
Beilstein6625414
MDL编号MFCD00210017

产品性质

质量水平200
等级anhydrous
测定99.99% trace metals basis
mp234-238 ℃ (lit.)
SMILES string[Li]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F
InChI1S/C2F6NO4S2.Li/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1
InChI keyQSZMZKBZAYQGRS-UHFFFAOYSA-N

安全信息

象形图GHS05GHS06GHS08
警示用语：Danger
危险声明H301 + H311 - H314 - H373 - H412
预防措施声明P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Oral
靶器官Nervous system
储存分类代码6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
010326FluorochemLithium Bis(trifluoromethanesulfonyl)imide99%396元/25g;   1496元/100g;   展开

基本信息

CAS Number90076-65-6
MDL NumberMFCD00210017
Melting Point231-239℃
Density2.15

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H311: Toxic in contact with skin.
H314: Causes severe skin burns and eye damage.
H373: May cause damage to organs ..
H412: Harmful to aquatic life with long lasting effects.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P314: Get medical advice/attention if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P361: Remove/Take off immediately all contaminated clothing.
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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