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CAS: 56881-90-4
分子式: C4H6O3
分子量: 102.09
沸点: 133℃(10
英文名称: 
(R)-(+)-alpha-hydroxy-gamma-butyrolactone
推荐供应商
货号品牌产品名称规格包装、参考价格详情
R863096MACKLIN(R)-(+)-α-羟基-γ-丁内酯≥98%(GC)131元/10mg;   展开
储存:室温,干燥
状态:无色-微浅黄色透明液体
H0950TCI(R)-(+)-α-Hydroxy-γ-butyrolactone>98.0%(GC)690元/100MG;   4500元/1G;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C4H6O3 = 102.09
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
Reaxys-RN80588
PubChem物质ID87571306
MDL编号MFCD00211246

技术规格

AppearanceColorless to Light yellow clear liquid
Purity(GC)min. 98.0 %
Optical purity(GC)min. 96.0 ee%
Specific rotation [a]20/D+67.0 to +76.0 deg(C=1, CHCl3)

物性(参考值)

沸点133 ℃/10 mmHg
比重1.32
比旋光度 [α]D71.5° (C=1,CHCl3)
折射率1.47
444286Sigma-Aldrich(R)-(+)-α-Hydroxy-γ-butyrolactone95%, optical purity ee: 98% (GLC)1148.86元/1 G;   展开

产品说明

应用

(R)-(+)-α-Hydroxy-γ-butyrolactone can be used as a starting material to synthesize:

  • δ-Azaproline by reacting with benzyloxycarbonyl aminophthalimide via Mitsunobu reactions.
  • Homochiral (R)-2,4-dihydroxybutyramide seco-pseudonucleoside reagents.
  • Botryolide B via esterification and ring-closing metathesis reaction.
  • Pregnane derivatives containing γ-butyrolactones as potential glucocorticoid agonists.

包装

1 g in glass bottle

基本信息

经验(实验)分子式C4H6O3
分子量102.09
Beilstein80588
MDL编号MFCD00211246
PubChem化学物质编号24868111
NACRESNA.22

产品性质

质量水平100
测定95%
旋光性[α]23/D +66°, c = 1.15 in chloroform
光学纯度ee: 98% (GLC)
折射率n20/D 1.467 (lit.)
bp133 ℃/10 mmHg (lit.)
密度1.309 g/mL at 25 ℃ (lit.)
SMILES stringO[C@@H]1CCOC1=O
InChI1S/C4H6O3/c5-3-1-2-7-4(3)6/h3,5H,1-2H2/t3-/m1/s1
InChI keyFWIBCWKHNZBDLS-GSVOUGTGSA-N

安全信息

储存分类代码12 - Non Combustible Liquids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves
238941Fluorochem(R)-3-Hydroxydihydrofuran-2(3H)-one95%14564元/1g;   展开

基本信息

CAS Number56881-90-4
MDL NumberMFCD00211246
Boiling Point133℃/
Density1.32

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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