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CAS: 5570-19-4
分子式: C6H6BNO4
分子量: 166.93
熔点: 155-160°C
中文名称: 
2-硝基苯硼酸
2-硝基苯基硼酸
英文名称: 
C6H6BNO4
(2-nitrophenyl)boronic acid
2-Nitrophenylboronic acid
2-Nitrobenzeneboronic acid
推荐供应商
货号品牌产品名称规格包装、参考价格详情
N823460MACKLIN2-硝基苯硼酸98%28元/1g;   60元/5g;   299元/25g;   展开
储存:2~8℃
状态:白色到橙色到棕色粉末或晶体
N0811TCI2-Nitrophenylboronic Acid (contains varying amounts of Anhydride)380元/1G;   1590元/5G;   展开

基本信息

分子式/分子量C6H6BNO4 = 166.93
外观与形状(20℃)固体
Reaxys-RN3032097
PubChem物质ID87559884
MDL编号MFCD00161358

技术规格

AppearanceWhite to Yellow to Orange powder to crystal
Purity(Neutralization titration)97.0 to 112.0 %

物性(参考值)

熔点142 ℃
溶解性(可溶于)甲醇,乙醚,乙醇

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
218162J&K2-Nitrophenylboronic acid97%249元/1G;   897元/5G;   展开

基本信息

分子式C6H6BNO4
分子量166.93
熔点155-160
MDL编码MFCD00161358
Beilstein3032097

安全信息

图形或危害标志
提示语Warning
危险说明H302
H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA
L17988Alfa Aesar2-Nitrobenzeneboronic acid96%1347元/1g;   6306元/5g;   展开

基本信息

MDL
MFCD00161358

分子式
C6H6BNO4

分子量
166.93

熔点
149-151°

Beilstein
3032097

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

673862Sigma-Aldrich2-Nitrophenylboronic acid≥95%573.7元/1 G;   展开

产品说明

应用

Boronic acid catalyst used for:

  • Mild and selective dipolar cycloadditions of unsaturated carboxylic acids with azides
  • Transposition of allylic alcohols and Meyer-Schuster rearrangements

Reactant involved in:
  • Suzuki-Miyaura cross-coupling reactions with aryl halides or nitroarenediazonium tetrafluoroborates
  • Copper-catalyzed halogenation
  • Oxidative arylation of aminopyrazolyl disulfides

用于与硝基苯卤化物通过 Suzuki-Miyaura 交叉偶联反应制备不对称 2,2′-二硝基联苯。

包装

1, 5 g in glass bottle

其他说明

可能含不定量的酸酐

基本信息

线性分子式(O2N)C6H4(B(OH)2)
分子量166.93
MDL编号MFCD00161358
PubChem化学物质编号24885182
NACRESNA.22

产品性质

质量水平100
测定≥95%
形式powder
mp155-160 ℃
SMILES stringOB(O)c1ccccc1[N+]([O-])=O
InChI1S/C6H6BNO4/c9-7(10)5-3-1-2-4-6(5)8(11)12/h1-4,9-10H
InChI keySFUIGUOONHIVLG-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H315 - H319 - H335
预防措施声明P261 - P264 - P270 - P301 + P312 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
016265Fluorochem2-Nitrophenylboronic acid96%352元/1g;   1056元/5g;   3300元/25g;   展开

基本信息

CAS Number5570-19-4
MDL NumberMFCD00161358
Melting Point155 - 160 ℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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