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CAS: 505-23-7
分子式: C4H8S2
分子量: 120.24
沸点: 207-208°C
熔点: 49-54℃
中文名称: 
1,3-二噻环己烷
1,3-二噻烷
英文名称: 
1,3-Dithian
[1,3]Dithiane
m-Dithiane
1,3-Dithiacyclohexane
1,3-Dithiane
dithiane-1,3
性质描述: 白色晶体。熔点54℃。能升华。
生产方法: 将三氟化硼乙醚溶液、冰乙酸和氯仿的混合物,在剧烈搅拌下加热回流,滴加1,3-丙二硫醇和甲醛缩二甲醇-氯仿溶液。然后冷至室温。依次用水、10%氢氧化钾溶液、水洗涤。分出氯仿溶液进行干燥、浓缩,残余物溶于甲醇,加热至沸,趁热过滤,滤液冷至室温,置-20℃静置过夜,滤出结晶,真空干燥,得1,3-二噻烷。
用途: 用于有机合成。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
D742619MACKLIN1,3-二噻烷Standard for GC, ≥99.8%(GC)270元/1g;   展开
储存:室温
状态:固体
D808547MACKLIN1,3-二噻烷98%29元/1g;   56元/5g;   250元/25g;   965元/100g;   4806元/500g;   展开
储存:室温
状态:白色到黄色粉末,针状和/或块状
D0119TCI1,3-Dithiane>97.0%(GC)455元/5G;   1835元/25G;   展开

基本信息

纯度/分析方法>97.0%(GC)
分子式/分子量C4H8S2 = 120.23
外观与形状(20℃)固体
Reaxys-RN102534
PubChem物质ID87566857
SDBS (AIST Spectral DB)15370
MDL编号MFCD00006654

技术规格

AppearanceWhite to Light yellow to Light orange powder to crystal
Purity(GC)min. 97.0 %
Melting point52.0 to 55.0 ℃

物性(参考值)

熔点53 ℃
沸点208 ℃

相关法规

RTECS#JO5070000
259418J&K1,3-Dithiane98%310元/5G;   1245元/25G;   4750元/100G;   展开

基本信息

分子式C4H8S2
分子量120.24
熔点52-54
闪点90
MDL编码MFCD00006654
Beilstein102534
EINECS 编号208-006-7

安全信息

防范说明P262
WGK3
RTECSJO5070000
TSCA
A10505Alfa Aesar1,3-Dithiane98%1055元/5g;   2902元/25g;   13005元/100g;   展开

应用
1,3-Dithiane is used in umpolung reactions such as the Corey-Seebach reaction. It acts as a reagent for the deoxygenation of sulfoxides to their corresponding sulfides. Further, it is used as a protecting group for carbonyl compounds used in organic synthesis. It serves as a useful labeled synthon. In addition to this, it is used in the preparation of 2-ethyl-[1,3]dithiane.

备注
Hygroscopic. Incompatible with strong bases and strong oxidizing agents.

基本信息

MDL
MFCD00006654

EINECS
208-006-7

分子式
C4H8S2

分子量
120.24

熔点
52-55°

沸点
207-208°

闪点
90°(194°F)

灵敏度
Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in benzene, ether, chloroform and terahydrofuran. Slightly soluble in water.

Beilstein
102534

安全信息

RTECS
JO5070000

TSCA

157872Sigma-Aldrich1,3-Dithiane97%478.83元/5 G;   1662.13元/25 G;   展开

产品说明

一般描述

1,3-二噻烷,一种受保护的甲醛阴离子当量,用作有用的标记合成子。

应用

以 1,3-二噻烷为脱氧剂,将亚砜脱氧成相应的硫化物。

包装

1, 5, 25 g in glass bottle

基本信息

经验(实验)分子式C4H8S2
分子量120.24
Beilstein102534
EC 号208-006-7
MDL编号MFCD00006654
PubChem化学物质编号24849705
NACRESNA.22

产品性质

质量水平100
测定97%
mp52-54 ℃ (lit.)
SMILES stringC1CSCSC1
InChI1S/C4H8S2/c1-2-5-4-6-3-1/h1-4H2
InChI keyWQADWIOXOXRPLN-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)194.0 °F - closed cup
闪点(C)90 ℃ - closed cup
个人防护装备Eyeshields, Gloves, type N95 (US)
978482Amethyst1,3-Dithiane98%, 用于合成40元/1G;   110元/5G;   398元/25G;   1435元/100G;   展开

基本信息

分子式C4H8S2
分子量120.24
熔点52-54
闪点90
MDL编码MFCD00006654
Beilstein102534
EINECS 编号208-006-7

安全信息

防范说明P262
WGK3
RTECSJO5070000
TSCA
214605Fluorochem1,3-Dithiane95%220元/1g;   462元/5g;   836元/10g;   1914元/25g;   展开

基本信息

CAS Number505-23-7
MDL NumberMFCD00006654
Melting Point52 - 54

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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