CAS 36042-94-1; Chlorodi(o-tolyl)phosphine

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D854491

MACKLIN

二邻甲苯基氯化膦

98%

1795元/1g;

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储存：2-8°C, 惰性气体
状态：白色到黄色浑浊粘稠液体或固体

15-1815

Strem

Di-o-tolylchlorophosphine

min. 98%

945元/1g; 3450元/5g;

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H25890

Alfa Aesar

Chlorodi(o-tolyl)phosphine

98%

1187元/1g; 10228元/5g;

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应用
Chlorodi(o-tolyl)phosphine is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dye stuff.

备注
Air and moisture sensitive. Incompatible with oxidizing agents, bases, water/ moisture.

基本信息

MDL
MFCD04038733

EINECS
000-000-0

分子式
C₁₄H₁₄ClP

分子量
248.69

熔点
57°

沸点
174-178°/3mm

灵敏度
Moisture Sensitive. Air Sensitive. Store under Nitrogen. Ambient temperatures.

形态
Crystalline powder

溶解性
Not miscible or difficult to mix in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
34
Causes burns.

安全等级
20-26-36/37/39-45
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA
否

686697

Sigma-Aldrich

Chlorodi(o-tolyl)phosphine

618.81元/1 G; 1993.7元/5 G;

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基本信息

经验(实验)分子式	C₁₄H₁₄ClP
分子量	248.69
MDL编号	MFCD04038733
PubChem化学物质编号	329761066
NACRES	NA.22

产品性质

reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand
质量水平	100
mp	63-67 ℃
官能团	phosphine
SMILES string	Cc1ccccc1P(Cl)c2ccccc2C
InChI	1S/C14H14ClP/c1-11-7-3-5-9-13(11)16(15)14-10-6-4-8-12(14)2/h3-10H,1-2H3
InChI key	KAAGXBGJRWFWPT-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H314
预防措施声明	P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
危险分类	Skin Corr. 1B
储存分类代码	8A - Combustible, corrosive hazardous materials
WGK	WGK 3
闪点(F)	230.0 °F - closed cup
闪点(C)	> 110 ℃ - closed cup
个人防护装备	Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges