基本信息

技术规格

物性(参考值)

安全信息

图形或危害标志
信号词	危险
危险性说明	H302 : 吞咽有害。 H314 : 造成严重皮肤灼伤和眼损伤。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P260 : 不要吸入粉尘或烟雾。 P270 : 使用本产品时不要进食、饮水或吸烟。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。 P301 + P330 + P331 : 如误吞咽：漱口。不要诱导呕吐。 P363 : 沾染的衣服清洗后方可重新使用。 P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。 P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。 P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。 P405 : 存放处须加锁。

运输信息

应用
It is applied in the abstraction of the ?-H atom of alcohols and their O-substituted derivatives results in oxidation to the ketones and in the oxidation of TMS ethers to ketones, secondary alcohols to ketones, and secondary diols to ?-hydroxy ketones. It is applied as a reactant involved in the synthesis of substituted dihydroazulene photo switches, carbene-based Lewis pairs for hydrogen activation, 1,3-Dipolar cycloaddition reactions for preparation of α-amino-β-hydroxy esters, oxidation of allenic compounds, Mukaiyama aldol addition reactions and ionic hydrogenation as a counteranion and ligand source.

备注
Moisture sensitive. Store away from bases, water/moisture, heat and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas. Keep it refrigerated.

基本信息

MDL
MFCD00013120

EINECS
206-433-3

分子式
C₁₉H₁₅BF₄

分子量
330.13

熔点
ca 207° dec.

灵敏度
Keep Cold. Moisture Sensitive. Store under Nitrogen.

形态
Powder

溶解性
Insoluble in water. Soluble in methanol.

Beilstein
5085649

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P280-P303+P361+P353-P305+P351+P338-P310
Wear protective gloves/protective clothing/eye protection/face protection.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Immediately call a POISON CENTER or doctor/physician.

安全信息

危险等级
8

包装组
II

危险类别
34
Causes burns.

安全等级
20-26-36/37/39-45-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
是

基本信息

Ref#
17295

MDL
13120

分子式
C19 H15 . B F4

分子量
330.13

形态
Powder

安全信息

危险等级
8

包装组
II

产品说明

应用

反应物可参与：

• 取代 dihydroazulene 光电开关的合成
• 用于氢活化的基于卡宾的路易斯酸碱对
• 用于制备 α−氨基-β-羟基酯的 1，3-偶极环加成反应
• 丙二醇化合物的氧化
• Mukaiyama aldol 加成反应
• 在离子氢化中作为一种抗衡离子和配体源

包装

5, 25 g in poly bottle

基本信息

产品性质

安全信息

象形图
警示用语：	Danger
危险声明	H314
预防措施声明	P280 - P305 + P351 + P338 - P310
危险分类	Skin Corr. 1B
补充剂危害	EUH014
储存分类代码	8B - Non-combustible, corrosive hazardous materials
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges