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CAS: 3153-26-2
分子式: C10H14O5V
分子量: 265.16
熔点: 256-259℃
中文名称: 
氧化钒(Ⅳ)乙酰丙酮
英文名称: 
Vanadium,oxobis(2,4-pentanedionato-O,O')-,(SP-5-21)-
oxobis(2,4-pentanedionato-O,O')-, (SP-5-21)-Vanadium
4-pentanedionato-o,o')- oxobis( (sp-5-21)-vanadiu
vanadyl(iv)-acetylacetonate
Oxy-bis(2,4-pentandione)-vanadium
Oxy-bis2,4-pentandione-vanadium
推荐供应商
货号品牌产品名称规格包装、参考价格详情
V820451MACKLIN乙酰丙酮氧钒99%30元/2g;   52元/10g;   98元/50g;   323元/250g;   1260元/1kg;   5407元/5kg;   展开
储存:室温,密封
状态:蓝色到绿色粉末或晶体
V0016TCIBis(2,4-pentanedionato)vanadium(IV) Oxide>95.0%(T)450元/25G;   展开

基本信息

纯度/分析方法>95.0%(T)
分子式/分子量C10H14O5V = 265.16
外观与形状(20℃)固体
PubChem物质ID87577816
SDBS (AIST Spectral DB)4158
MDL编号MFCD00000032

技术规格

AppearanceBlue to Dark blue powder to crystal
Purity(Chelometric Titration)min. 95.0 %

物性(参考值)

溶解性(可溶于)氯仿

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
119999J&KVanadyl(IV) acetylacetonate98%120元/10G;   372元/50G;   1029元/250G;   展开

基本信息

分子式C10H14O5V
分子量265.16
熔点235
MDL编码MFCD00000032
Beilstein4138236
EINECS 编号221-590-8

安全信息

图形或危害标志
提示语Warning
危险说明H302
H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA
162797J&KVanadyl(IV) acetylacetonate99%122元/10G;   487元/50G;   1945元/250G;   展开

基本信息

分子式C10H14O5V
分子量265.16
熔点240-242
MDL编码MFCD00000032
Beilstein4138236
EINECS 编号221-590-8

安全信息

图形或危害标志
提示语Warning
危险说明H302
H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA
23-2202StremVanadium(IV) bis(acetylacetonato)oxide98%792元/50g;   2025元/250g;   展开

Technical Notes:

1.Catalyst for the hydroxyl-directed epoxidation of olefins.

2. Catalyst for the asymmetric oxidation of disulfides.

3. Catalyst for the Mannich reaction.

4. Catalyst for sulfoxidation of alkanes.

References: 1. Chem. Rev., 1993, 93, 1307. 2.Org. L ett., 2009, 1 1, 2896. 3.J. Am. Chem. Soc., 1998, 120, 801 1. 4.Org. L ett., 2002, 4, 463. 5.C hem.Comm.,009,3169. 6.J. Am. ( hem. Soc., 2000, 122, 7390. 7.J. Am. ( hem. Soc., 2001, 123, 1 545.
081119Alfa AesarVanadium(IV) oxide bis(2,4-pentanedionate)288元/10g;   1100元/50g;   2909元/250g;   展开

应用
Employed as a catalyst, as a synthesis intermediate, as a paint dryer, and as a pigment. It is used in organic chemistry as a reagent in the epoxidation of allylic alcohols in combination with tert-butyl hydroperoxide (TBHP).

备注
Keep away from oxidizing agents.

基本信息

MDL
MFCD00000032

EINECS
221-590-8

分子式
C10H14O5V

分子量
265.16

熔点
256-259°

沸点
140°/13mm

密度
1.4

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Moderately soluble in acetone, ether and chloroform. Soluble in ethanol and benzene

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H315-H319-H335
Toxic if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P301+P310a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
25-36/37/38
Toxic if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
20-26-36/37-45
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

TSCA

C19959Alfa AesarVanadyl(IV) acetylacetonate99%1426元/50g;   3763元/250g;   11066元/1kg;   展开

基本信息

Ref#
19959

MDL
32

分子式
C10 H14 O5 V

分子量
265.15

闪点
79

安全信息

危险等级
6.1

包装组
III

550787Sigma-AldrichVanadyl Acetylacetonate98%546.1元/10 G;   955.36元/50 G;   展开

产品说明

应用

乙酰丙酮氧钒可用作制备二氧化钒薄膜的前体,用于“智能”窗户涂层和数据存储。

包装

10, 50 g in poly bottle

基本信息

线性分子式OV(C5H7O2)2
分子量265.16
Beilstein4138236
EC 号221-590-8
MDL编号MFCD00000032
PubChem化学物质编号24879146
NACRESNA.23

产品性质

质量水平100
测定98%
形式solid
mp235 ℃ (dec.) (lit.)
SMILES stringCC(=O)\C=C(\C)O[V](=O)O\C(C)=C/C(C)=O
InChI1S/2C5H8O2.O.V/c2*1-4(6)3-5(2)7;;/h2*3,6H,1-2H3;;/q;;;+2/p-2/b2*4-3-;;
InChI keyJFHJZWAQYMGNBE-SUKNRPLKSA-L

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H315 - H319 - H335
预防措施声明P261 - P264 - P270 - P301 + P312 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
8.08505Sigma-AldrichVanadium(IV) oxide acetylacetonatefor synthesis624.18元/100 G;   展开

产品说明

分析说明

Assay (ex V): ≥ 98.0 %
Identity (IR): passes test

基本信息

经验(实验)分子式C10H14O5V
分子量265.16
MDL编号MFCD00000032
EC索引号221-590-8

产品性质

质量水平200
mp243-246 ℃
溶解性 10 g/L
堆积密度450 kg/m3
储存温度2-30℃
InChI1S/2C5H8O2.O.V/c2*1-4(6)3-5(2)7;;/h2*3H2,1-2H3;;
InChI keyGGUKAPURIDGXAJ-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H315 - H319 - H335
预防措施声明P261 - P264 - P270 - P301 + P312 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
94735Sigma-AldrichVanadyl Acetylacetonatepurum, ≥97.0% (RT)909.29元/50 G;   展开

基本信息

线性分子式OV(C5H7O2)2
分子量265.16
Beilstein4138236
EC 号221-590-8
MDL编号MFCD00000032
PubChem化学物质编号329770380
NACRESNA.23

产品性质

质量水平200
等级purum
测定≥97.0% (RT)
形式solid
reaction suitabilityreagent type: catalyst
mp235 ℃ (dec.) (lit.)
SMILES stringCC(=O)\C=C(\C)O[V](=O)O\C(C)=C/C(C)=O
InChI1S/2C5H8O2.O.V/c2*1-4(6)3-5(2)7;;/h2*3,6H,1-2H3;;/q;;;+2/p-2/b2*4-3-;;
InChI keyJFHJZWAQYMGNBE-SUKNRPLKSA-L

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H315 - H319 - H335
预防措施声明P261 - P264 - P270 - P301 + P312 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
171855AmethystVanadyl(IV) acetylacetonate98%, 用于合成60元/10G;   122元/50G;   459元/250G;   展开

基本信息

分子式C10H14O5V
分子量265.16
熔点235
MDL编码MFCD00000032
Beilstein4138236
EINECS 编号221-590-8

安全信息

图形或危害标志
提示语Warning
危险说明H302
H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA
463488FluorochemVanadyl Acetylacetonate95%286元/25g;   924元/100g;   展开

基本信息

CAS Number3153-26-2
MDL NumberMFCD00000032
Melting Point256-259℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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