CAS 1530-45-6; (乙氧基羰基甲基)三苯基溴化膦; Ethyl(triphenylphosphonio)acetate bromide

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E808913

MACKLIN

(乙氧基羰基甲基)三苯基溴化膦

98%

29元/5g; 45元/25g; 140元/100g; 668元/500g;

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储存：2~8 °C
状态：白色到灰白色粉末,晶体和/或块状

E0407

TCI

Ethoxycarbonylmethyl(triphenyl)phosphonium Bromide

>97.0%(T)

250元/25G; 1770元/250G;

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基本信息

纯度/分析方法	>97.0%(T)
分子式/分子量	C₂₂H₂₂BrO₂P = 429.29
外观与形状(20℃)	固体
Reaxys-RN	3581273
PubChem物质ID	87569664
SDBS (AIST Spectral DB)	23422
MDL编号	MFCD00011835

技术规格

Appearance	White to Light yellow to Light orange powder to crystal
Purity(Nonaqueous Titration)	min. 97.0 %

物性(参考值)

熔点	158 ℃
溶解性(可溶于)	甲醇

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。

相关法规

RTECS#

TA2299500

196483

J&K

(Carbethoxymethyl)triphenylphosphonium bromide

98%

133元/25G; 459元/100G;

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基本信息

分子式	C₂₂H₂₂BrO₂P
分子量	429.29
熔点	145-150
MDL编码	MFCD00011835
Beilstein	3581273
EINECS 编号	216-230-1

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3
RTECS	TA2299500
TSCA	否

A16347

Alfa Aesar

(Ethoxycarbonylmethyl)triphenylphosphonium bromide

98+%

826元/25g; 2210元/100g; 10021元/500g;

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应用
(Ethoxycarbonylmethyl)triphenylphosphonium bromide, is used as a pharmaceutical intermediate.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from Strong oxidizing agents, Strong bases.

基本信息

MDL
MFCD00011835

EINECS
216-230-1

分子式
CH₃CH₂O₂CCH₂P(C₆H₅)₃Br

分子量
429.30

熔点
ca 150° dec.

灵敏度
Hygroscopic. Ambient temperatures.

形态
Powder

溶解性
It is soluble in water.

Beilstein
3581273

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

RTECS
TA2299500

TSCA
否

C10830

Alfa Aesar

(Carbethoxymethyl)triphenylphosphonium bromide

98%

1026元/25g;

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基本信息

Ref#
10830

MDL
11835

分子式
C22 H22 Br O2 P

分子量
429.28

412252

Sigma-Aldrich

(Ethoxycarbonylmethyl)triphenylphosphonium bromide

98%

460.88元/100 G;

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产品说明

应用

Reactant for:

Wittig olefination reactions for synthesis of tetramic acid derivatives
Synthesis of precursors for Bergman cyclization
Preparation of PPAR agonists derived from thalidomide-related LXR antagonists
Synthesis of benzoxaboroles with antimalarial activity
Michael acceptor based cysteine protease inhibitors
Mechanistic studies of the IspH reductase protein

包装

100 g in poly bottle

基本信息

线性分子式	CH₃CH₂OCOCH₂P(C₆H₅)₃Br
分子量	429.29
Beilstein	3581273
EC 号	216-230-1
MDL编号	MFCD00011835
PubChem化学物质编号	24865798
NACRES	NA.22

产品性质

质量水平	100
测定	98%
reaction suitability	reaction type: C-C Bond Formation
mp	145-150 ℃ (dec.) (lit.)
SMILES string	[Br-].CCOC(=O)C[P+](c1ccccc1)(c2ccccc2)c3ccccc3
InChI	1S/C22H22O2P.BrH/c1-2-24-22(23)18-25(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h3-17H,2,18H2,1H3;1H/q+1;/p-1
InChI key	VJVZPTPOYCJFNI-UHFFFAOYSA-M

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

049919

Fluorochem

Ethoxycarbonylmethyl-triphenyl-phosphonium bromide

98%

220元/1g; 264元/25g; 572元/100g; 2552元/500g;

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基本信息

CAS Number	1530-45-6
MDL Number	MFCD00011835
Melting Point	158℃

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .