CAS 15243-33-1; 十二羰基三铷; dodecacarbonyltri-rutheniu triangulo

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T833294

MACKLIN

十二羰基三钌

98%

207元/200mg; 917元/1g; 3561元/5g; 7065元/25g;

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储存：室温,干燥
状态：橙色固体

T2181

TCI

Triruthenium Dodecacarbonyl

440元/100MG; 2490元/1G;

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基本信息

分子式/分子量	C₁₂O₁₂Ru₃ = 639.33
外观与形状(20℃)	固体
包装和容器	1G-带有塑料内管的玻璃瓶 (查看图片)
Reaxys-RN	14281346
PubChem物质ID	87558750
MDL编号	MFCD00011209

技术规格

Appearance	Orange to Brown powder to crystal
Elemental analysis(Carbon)	22.00 to 23.00 %

物性(参考值)

熔点	145 ℃(dec.)
最大吸收波长	393(EtOAc) nm

安全信息

图形或危害标志
信号词	警告
危险性说明	H332 : 吸入有害。
防范说明	P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。 P271 : 只能在室外或通风良好之处使用。 P304 + P340 + P312 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。如感觉不适，呼叫急救中心/医生。

526096

J&K

Triruthenium Dodecacarbonyl

99%

955元/1G; 3620元/5G;

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基本信息

分子式	C₁₂O₁₂Ru₃
分子量	639.33
熔点	150
MDL编码	MFCD00011209
EINECS 编号	239-287-4

安全信息

图形或危害标志
提示语	Warning
危险说明	H332
防范说明	P262
UN号码	3178
危险分类	4.1
包装等级	III
WGK	3
TSCA	是

44-1850

Strem

Ruthenium Carbonyl

99%

1279元/1g; 5533元/5g; 25350元/25g;

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Technical Notes:

1. Catalyst for the conversion of enynes to catechol derivatives .

2.Catalyst for the intermolecular 2 +2+1 cycloaddition of ketones, co and alkenes or alkynes.

3.3-Component couplings .

4.Reaction of a,ß-uns aturated imines with carbon monoxide and alkenes to form ß,v-unsaturated y butyroactams. 5.Ester decarboxylation .

6.Catalyst for hydroamination and C-H bond activation.

7.Used in sp3 C-H bond arylation and carbonylation.

8. Ru/halide catalytic system for c-C bond forming reaction between alkynes and unsaturated carbonyl compounds . 9. Amination of a-hydroxy amides.

References: 1.J. Am. Chem. Soc., 1993, 1 15, 1 1614. 2.J. Am. Chem. Soc., 2000, 122, 12663. 3.Chem. Commun., 2002, 2868. 4.J. Org. Chem., 2002, 67, 7014. 5.J.Am. Chem. Soc., 2001 , 1 23, 4849. 6.J.Am.Chem Soc., 2005, 127, 5782. 7.J. Am. Chem. Soc., 2006, 128, 14220. 8.Adv. Synth. Catal., 2007, 349, 2563. 9.J. Am. Chem. Soc., 2011, 133, 8070. 10Angew. Chem. Int. Ed., 2011, 50, 11197

010507

Alfa Aesar

Dodecacarbonyltriruthenium

99%

2466元/1g; 9272元/5g;

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应用
A H-transfer catalyst. It is used in carbonylation catalysis of the allylic amination of unactivated olefins by nitroarenes, reductive carbonylation of mononitro aromatic compounds to carbamates, and as a catalyst for cycloaddition reactions. It is employed as a precursor for the synthesis of Ru nanoparticles. Catalyst used in the intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide, to produce alpha-pyrones. Catalyzes the coupling of silanes with thiols, alcohols and amines with high turnover number (TON) and high turnover frequency (TOF).

备注
Incompatible with strong oxidizing agents. Solutions undergo decomposition at high temperatures.

基本信息

MDL
MFCD00011209

EINECS
239-287-4

分子式
C₁₂O₁₂Ru₃

分子量
639.33

熔点
ca 150° dec.

灵敏度
Ambient temperatures.

形态
Crystalline

溶解性
Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone.

GHS危害和防范说明

GHS符号

Hazard Statements
H331
Toxic if inhaled.

Precautionary Statements
P261-P304+P340-P311a-P405-P403+P233-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Store in a well-ventilated place. Keep container tightly closed.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
23
Toxic by inhalation.

安全等级
9-36-45-60
Keep container in a well-ventilated place.Wear suitable protective clothing.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

TSCA
是

C22400

Alfa Aesar

Triruthenium Dodecacarbonyl

99%

1614元/1g; 7183元/5g;

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基本信息

Ref#
22400

MDL
11209

分子式
C12 O12 Ru3

分子量
639.33

形态
Crystalline

245011

Sigma-Aldrich

Triruthenium Dodecacarbonyl

99%

1476.53元/1 G; 4093.33元/5 G; 32063.2元/50 G;

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产品说明

一般描述

基础材料的原子序数：44钌

包装

1, 5, 50 g in glass bottle

应用

作为催化剂用于硅基乙炔类化合物与 α,ß-不饱和酮的 [3+2+1] 羰基环加成反应，以高收率得到 α-吡喃酮。
羰基簇合物的前体和氢转移催化剂。用于芳族硝基化合物的还原羰基化反应生成氨基甲酸酯。已将膦稳定的羰基簇合物连到氧化物载体上。在通过芳硝基化合物进行的未活化烯烃的烯丙基胺化反应中用于获得改进的催化效果。

其他说明

一种将伯酰胺、仲酰胺和叔酰胺还原成胺的实用方法

基本信息

线性分子式	Ru₃(CO)₁₂
分子量	639.33
EC 号	239-287-4
MDL编号	MFCD00011209
PubChem化学物质编号	24854727
NACRES	NA.22

产品性质

质量水平	100
测定	99%
形式	crystals
reaction suitability	core: ruthenium reagent type: catalyst
SMILES string	[Ru].[Ru].[Ru].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
InChI	1S/12CO.3Ru/c12*1-2;;;
InChI key	NQZFAUXPNWSLBI-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H332
预防措施声明	P261 - P271 - P304 + P340 + P312
危险分类	Acute Tox. 4 Inhalation
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

050116

Fluorochem

Ruthenium Carbonyl

98%

1232元/1g; 3960元/5g;

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基本信息

CAS Number	15243-33-1
MDL Number	MFCD00011209
Melting Point	150℃

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H332: Harmful if inhaled.
防范说明	P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P362: Take off contaminated clothing and wash before reuse.