CAS 152329-44-7; (2-naphthylmethyl)zinc bromide solution

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详情

499021

Sigma-Aldrich

(2-Naphthylmethyl)zinc bromide solution

0.5 M in THF

1817.36元/50 ML;

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产品说明

一般描述

(2-Naphthylmethyl)zinc bromide is an organozinc halide, which is typically used as a reagent in Negishi cross-coupling reactions. In this process, the organozinc halide reacts with organic halides or triflates to form a carbon-carbon bond in the presence of a Pd catalyst.

应用

(2-Naphthylmethyl)zinc bromide can be used as a reagent for the synthesis of:

4-(5,6-dimethoxy-2-(naphthalen-2-ylmethyl)pyridin-3-yl)benzonitrile from 4-(2-bromo-5,6-dimethoxypyridin-3-yl)benzonitrile using Pd catalyst.
(E)-stilbene, (2,2′-[1,4-phenylenedi-(1E)-2,1-ethenediyl]bis[naphthalene]) from 1,4-benzenedicarboxaldehyde in the presence of Pd catalyst and a silylating agent.

包装

50 mL in Sure/Seal™

法律信息

Rieke® Metals, Inc. 产品 ®Rieke Metals, Inc. 的注册商标

基本信息

线性分子式	C₁₀H₇CH₂ZnBr
分子量	286.48
MDL编号	MFCD01311438
PubChem化学物质编号	24873248
NACRES	NA.22

产品性质

质量水平	100
浓度	0.5 M in THF
密度	0.978 g/mL at 25 ℃
储存温度	2-8℃
SMILES string	Br[Zn]Cc1ccc2ccccc2c1
InChI	1S/C11H9.BrH.Zn/c1-9-6-7-10-4-2-3-5-11(10)8-9;;/h2-8H,1H2;1H;/q;;+1/p-1
InChI key	IKDINBHMSAHXCA-UHFFFAOYSA-M

安全信息

象形图
警示用语：	Danger
危险声明	H225 - H319 - H335 - H336 - H351
预防措施声明	P202 - P210 - P233 - P240 - P305 + P351 + P338 - P308 + P313
危险分类	Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2
补充剂危害	EUH014 - EUH019
储存分类代码	4.3 - Hazardous materials, which set free flammable gases upon contact with water
WGK	WGK 3
闪点(F)	1.4 °F - closed cup
闪点(C)	-17 ℃ - closed cup

213900

Fluorochem

(2-Naphthyl)methylzinc bromide 0.5 M in Tetrahydrofuran

8316元/50ml; 14608元/100ml;

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基本信息

CAS Number	152329-44-7
MDL Number	MFCD01311438