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CAS: 15201-61-3
分子式: FeCl3O12·xH2O
分子量: 354.20 (anhydrous basis)
中文名称: 
高氯酸铁水溶液
高氯酸铁(Ⅲ)九水
九水合高氯酸铁
九水合过氯酸铁
过氯酸高铁(九水)
英文名称: 
Aqueous ferric perchlorate
iron(iii) perchlorate hydrate
iron(iii)perchlorate hydrate
iron(iii)perchloratehydrate
Iron(Ⅲ)perchlorate
推荐供应商
货号品牌产品名称规格包装、参考价格详情
768329MACKLIN高氯酸铁 水合物≥95%520元/250mg;   1570元/1g;   7850元/5g;   展开
储存：室温, 惰性气体
I811768MACKLIN高氯酸铁 水合物65%258元/25g;   845元/100g;   展开
储存：室温
状态：黄色到棕色粉末或晶体
93-2620StremIron(III) perchlorate hydrate (yellow)405元/50g;   1635元/250g;   展开
93-2673StremIron(III) perchlorate hydrate (purple)405元/50g;   1485元/250g;   展开
011647Alfa AesarIron(III) perchlorate hydrateReagent Grade891元/100g;   2316元/500g;   展开

应用
Iron(III) perchlorate hydrate is used as a starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units that allow two coordination modes. It is also used as a catalyst for synthesis of fullerene-fused lactones, α-Carbonyl furans via one-pot cyclization, fullerodioxolanes via heterocyclization, dialylated indoles via double alkylation, aryl esters via oxidative esterification and as a chemical actinometer based on photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution, as an oxidant for conducting polymer nanoparticles synthesized in ionic liquid by chemical polymerization.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. It is hygroscopic in nature.

基本信息

MDL
MFCD00011000

EINECS
236-908-0

分子式
Fe(ClO4)3?xH2O

分子量
354.19(anhy)

灵敏度
Hygroscopic. Store under Nitrogen. Ambient temperatures.

形态
Crystalline

溶解性
Soluble in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H272-H315-H319-H335
May intensify fire; oxidizer.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P221-P210a-P220-P305+P351+P338-P405-P501a
Take any precaution to avoid mixing with combustibles.Keep away from heat. - No smoking.Keep/Store away from clothing/combustible materials.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
5.1

包装组
II

危险类别
8-36/37/38
Contact with combustible material may cause fire.Irritating to eyes, respiratory system and skin.

安全等级
17-26-37-60
Keep away from combustible material.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
是

309281Sigma-AldrichIron(III) perchlorate hydratecrystalline694.13元/100 G;   展开

产品说明

应用

用于合成以下物质的催化剂：

  • 富勒烯融合内酯
  • α-羰基呋喃的一锅法环化反应
  • 通过杂环化反应生产富勒二恶烷
  • 通过双重烷基化的透析吲哚
  • 芳基酯的氧化酯化

用作水溶液中多金属氧酸盐存在下草酸铁光解的化学辐射计
离子液体中化学聚合法合成导电聚合物纳米粒子的氧化剂
用于合成具有允许两种配位模式的双齿螯合单元的三水杨酸铁 (III) 配合物的有用起始物料。
高氯酸盐水合物铁 (III) 是合成具有双齿螯合单元的 tris 水杨酸铁 (III) 络合物以及在水溶液中多金属氧酸盐存在下草酸铁光解的有用起始物料。

可作为合成以下物质的催化剂：
  • 富勒烯融合内酯
  • α-羰基呋喃(通过一锅法环化反应)
  • 通过杂环化反应生产富勒二恶烷
  • 富勒恶唑烷
  • 通过双烷基化透析吲哚
  • 芳基酯(通过氧化酯化)

包装

100 g in glass bottle

基本信息

线性分子式Fe(ClO4)3 · xH2O
分子量354.20 (anhydrous basis)
EC 号236-908-0
MDL编号MFCD00149705
PubChem化学物质编号24858725
NACRESNA.22

产品性质

形式crystalline
质量水平100
reaction suitabilityreagent type: oxidant
杂质<0.10% chloride
颜色 yellow
SMILES string[Fe+3].[H]O[H].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
InChI1S/3ClHO4.Fe.H2O/c3*2-1(3,4)5;;/h3*(H,2,3,4,5);;1H2/q;;;+3;/p-3
InChI keyPFPIMAZLJXJVAN-UHFFFAOYSA-K

安全信息

象形图GHS03GHS07
警示用语：Danger
危险声明H272 - H315 - H319 - H335
预防措施声明P210 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码5.1A - Strongly oxidizing hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
326348Sigma-AldrichIron(III) perchlorate hydratecrystalline, low chloride835.91元/100 G;   2441.33元/500 G;   展开

产品说明

应用

用于合成以下物质的催化剂：

  • 富勒烯融合内酯
  • α-羰基呋喃的一锅法环化反应
  • 通过杂环化反应生产富勒二恶烷
  • 通过双重烷基化的透析吲哚
  • 芳基酯的氧化酯化

用作水溶液中多金属氧酸盐存在下草酸铁光解的化学辐射计

离子液体中化学聚合法合成导电聚合物纳米粒子的氧化剂
用于合成三水杨酸铁络合物的原料，该络合物具有双齿螯合单元，具有两种配位模式。

包装

100, 500 g in glass bottle

基本信息

线性分子式Fe(ClO4)3 · xH2O
分子量354.20 (anhydrous basis)
EC 号236-908-0
MDL编号MFCD00149705
PubChem化学物质编号24859580
NACRESNA.22

产品性质

质量水平100
形式crystalline
reaction suitabilityreagent type: oxidant
杂质<0.005% chloride
颜色pale violet
SMILES string[Fe+3].[H]O[H].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
InChI1S/3ClHO4.Fe.H2O/c3*2-1(3,4)5;;/h3*(H,2,3,4,5);;1H2/q;;;+3;/p-3
InChI keyPFPIMAZLJXJVAN-UHFFFAOYSA-K

安全信息

象形图GHS03GHS07
警示用语：Danger
危险声明H272 - H315 - H319 - H335
预防措施声明P210 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码5.1A - Strongly oxidizing hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
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