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CAS: 15186-48-8
分子式: C6H10O3
分子量: 130.14
中文名称: 
(R)-(+)-2,2-二甲基-1,3-二氧-4-醛基戊烷
英文名称: 
(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde
2,3-o-isopropylidene- d-glyceraldehyde
(R)-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde
推荐供应商
货号品牌产品名称规格包装、参考价格详情
R931274MACKLIN(R)-(+)-2,2-二甲基-1,3-二氧戊环-4-甲醛50% in Chlorocyclohexane30元/5g;   79元/25g;   296元/100g;   展开
储存:-20°C
状态:无色到黄色澄清或浑浊液体
R931273MACKLIN(R)-(+)-2,2-二甲基-1,3-二氧戊环-4-甲醛97%36元/5g;   88元/25g;   320元/100g;   1599元/500g;   7880元/2.5kg;   展开
储存:-20°C
状态:无色到黄色液体或固体
R830825MACKLIN(R)-(+)-2,2-二甲基-1,3-二氧戊环-4-甲醛50% in Dichloromethane30元/5g;   79元/25g;   296元/100g;   1325元/500g;   展开
储存:-20℃
状态:无色至黄色透明或浑浊液体
C36926Alfa Aesar(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde97%3011元/1g;   展开

基本信息

Ref#
36926

MDL
269682

分子式
C6 H10 O3

分子量
130.14

闪点
62

密度
1045

454486Sigma-Aldrich(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde525.54元/500 MG;   展开

产品说明

应用

参与有机反应的反应物包括:

  • 亨利缩合反应
  • 高官能团手性氮杂环丙烷的合成
  • 醛的烯化
  • 氧化
  • Aldol 型冷凝
  • 外源荧光示踪剂用亲水性吡嗪染料的合成
  • Hosomi-Sakurai反应

包装

500 mg in amber glass bottle

基本信息

经验(实验)分子式C6H10O3
分子量130.14
MDL编号MFCD00269682
PubChem化学物质编号24868922
NACRESNA.22

产品性质

质量水平100
旋光性[α]22/D +53.8°, c = 2 in chloroform
折射率n20/D 1.454 (lit.)
bp139 ℃ (lit.)
密度1.045 g/mL at 25 ℃ (lit.)
储存温度−20℃
SMILES stringCC1(C)OC[C@@H](O1)C=O
InChI1S/C6H10O3/c1-6(2)8-4-5(3-7)9-6/h3,5H,4H2,1-2H3/t5-/m0/s1
InChI keyYSGPYVWACGYQDJ-YFKPBYRVSA-N

安全信息

储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)143.6 °F - closed cup
闪点(C)62 ℃ - closed cup
个人防护装备Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
038227Fluorochem(R)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde 50% in Methylene chloride95%704元/5g;   1540元/25g;   展开

基本信息

CAS Number15186-48-8
MDL NumberMFCD00269682
Boiling Point72-74℃
Density1.045

安全信息

图形或危害标志
危险性说明 H226: Flammable liquid and vapour.
H301: Toxic if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use sand, CO2 or extinguishing powder for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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