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CAS: 135-02-4
分子式: C8H8O2
分子量: 136.15
沸点: 238℃
熔点: 35-38℃
中文名称: 
水杨醛甲醚
邻甲氧基苯甲醛
2-甲氧基苯甲醛
邻茴香醛
英文名称: 
2-methoxy-benzaldehyde
o-Anisaldehyd
2-Methoxybenzaldehyde
2-Anisaldehyde
2-methoxy-Benzaldehyde
o-anisaldehyde
2-methoxybenzenecarboxaldehyde
6-methoxybenzaldehyde
Benzaldehyde,2-methoxy-
2-methoxy-benzaldehyd
o-methoxybenzaldehyde
salicylaldehyde methyl ether
展开更多英文名
性质描述: 无色棱形晶体。熔点39℃,沸点238℃,70-75℃/0.2kPa,相对密度1.1326(20/4℃),折光率1.5597,闪点117℃。溶于醇、醚、苯,不溶于水。与硫酸作用呈黄色。
生产方法: 由水杨醛经与硫酸二甲酯甲基化反应而制得。将3kg氢氧化钠配成30%水溶液,在搅拌下加入含12.2kg水杨醛和80L水的溶液中,加热至沸。将12.9kg硫酸二甲酯慢慢加入,使反应液保持回流约3h加完,继续回流2-3h,冷却油层,用5%氢氧化钠溶液洗涤,再用水洗至pH为8,加无水碳酸钾干燥。滤除干燥剂后减压蒸馏,收集120℃(2.0kPa)馏分,即为邻甲氧基苯甲醛。甲基化反应也可在溶剂甲苯中进行,收率60%。
用途: 该品为有机合成中间体,用于香料、医药的生产。邻甲氧基本甲醛可用于生产。邻甲氧基苯甲醛可用于生产拟肾上腺素药物喘咳宁。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
M813221MACKLIN2-甲氧基苯甲醛98%29元/25g;   33元/100g;   134元/500g;   660元/2.5kg;   展开
储存:室温,密封
状态:白色到黄色到棕色粉末,晶体或固体
折射率:1.5608
A0479TCIo-Anisaldehyde>98.0%(GC)180元/25G;   390元/100G;   1450元/500G;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C8H8O2 = 136.15
外观与形状(20℃)固体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN606301
PubChem物质ID87562094
SDBS (AIST Spectral DB)1680
MDL编号MFCD00003308

技术规格

AppearanceWhite or Colorless to Yellow to Orange powder to lump to clear liquid
Purity(GC)min. 98.0 %

物性(参考值)

熔点36 ℃
沸点243 ℃
折射率1.56

安全信息

图形或危害标志
信号词警告
危险性说明H303 : 吞咽可能有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P312 : 如感觉不适,呼叫急救中心/医生。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#BZ2610000
279079J&Ko-Anisaldehyde98%60元/5G;   61元/25g;   129元/100G;   566元/500G;   展开

基本信息

分子式C8H8O2
分子量136.15
熔点34-40
沸点238
闪点118
密度1.127
MDL编码MFCD00003308
Beilstein606301
Merck10,5866
EINECS 编号205-171-7

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK2
RTECSBZ2610000
A10770Alfa Aesar2-Methoxybenzaldehyde98%870元/100g;   3747元/500g;   16952元/2500g;   展开

应用
2-Methoxybenzaldehyde has been used to examine the acaricidal activity of Periploca sepium oil and its active component against Tyrophagus. It has also been used to obtain good enantioselectivities using Cu(OAc)(2)-bis(oxazolines) via hydrogen bonding in asymmetric Henry reaction.

备注
It is sensitive to air. Incompatible with oxidizing agents and bases.

基本信息

MDL
MFCD00003308

EINECS
205-171-7

分子式
C8H8O2

分子量
136.15

熔点
35-39°

沸点
237-238°

闪点
117°(242°F)

密度
1.13

折射率
1.5610

灵敏度
Air Sensitive. Ambient temperatures.

形态
Crystalline solid

溶解性
Insoluble in water.

Beilstein
606301

GHS危害和防范说明

GHS符号

Hazard Statements
H303-H315-H319
May be harmful if swallowed.Causes skin irritation.Causes serious eye irritation.

Precautionary Statements
P280g-P305+P351+P338
Wear protective gloves.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

安全信息

危险类别
36/38
Irritating to eyes and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

RTECS
BZ2610000

TSCA

C14922Alfa Aesaro-Anisaldehyde98%695元/5g;   1130元/100g;   4262元/500g;   展开

基本信息

Ref#
14922

MDL
3308

分子式
C8 H8 O2

分子量
136.15

闪点
117

W407701Sigma-Aldricho-Anisaldehyde≥97%, FG404.65元/;   2806.56元/1 KG;   3906.27元/5 KG;   7680.3元/10 KG;   展开

产品说明

包装

1 kg in glass bottle

生化/生理作用

10% pg 时的气味:
50ppm 水溶液的味道:
天然存在的具有杀螨活性的芳香醛。可与食物中的 L-色氨酸缩合生成相应的强力抗氧化剂酚醛四氢-β-咔啉-3-羧酸。

基本信息

线性分子式CH3OC6H4CHO
分子量136.15
FEMA编号4077
Beilstein606301
EC 号205-171-7
MDL编号MFCD00003308
PubChem化学物质编号329830674
Flavis编号5.129
NACRESNA.21

产品性质

质量水平400
生物来源synthetic
等级FG
Halal
Kosher
agencyfollows IFRA guidelines
reg. complianceEU Regulation 1223/2009
EU Regulation 1334/2008 & 872/2012
FDA 21 CFR 172.515
测定≥97%
bp238 ℃ (lit.)
mp34-40 ℃ (lit.)
密度1.127 g/mL at 25 ℃ (lit.)
文件see Safety & Documentation for available documents
性状检查almond; hawthorne; sweet; vanilla
application(s)flavors and fragrances
食品过敏原no known allergens
致敏芳香化合物no known allergens
SMILES string[H]C(=O)c1ccccc1OC
InChI1S/C8H8O2/c1-10-8-5-3-2-4-7(8)6-9/h2-6H,1H3
InChI keyPKZJLOCLABXVMC-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 2
闪点(F)244.4 °F - closed cup
闪点(C)118 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
1036948USPo-AnisaldehydeUnited States Pharmacopeia (USP) Reference Standard2219.35元/3 X 0.5 ML;   展开

产品说明

一般描述

This product is provided as delivered and specified by the issuing Pharmacopoeia. All information provided in support of this product, including SDS and any product information leaflets have been developed and issued under the Authority of the issuing Pharmacopoeia.
For further information and support please go to the website of the issuing Pharmacopoeia.

生化/生理作用

天然存在的具有杀螨活性的芳香醛。可与食物中的 L-色氨酸缩合生成相应的强力抗氧化剂酚醛四氢-β-咔啉-3-羧酸。

分析说明

These products are for test and assay use only. They are not meant for administration to humans or animals and cannot be used to diagnose, treat, or cure diseases of any kind.  ​

其他说明

USP issued SDS can be found here.
Sales restrictions may apply.

基本信息

线性分子式CH3OC6H4CHO
分子量136.15
Beilstein606301
MDL编号MFCD00003308
PubChem化学物质编号329749037
NACRESNA.24

产品性质

等级pharmaceutical primary standard
manufacturer/tradenameUSP
bp238 ℃ (lit.)
mp34-40 ℃ (lit.)
密度1.127 g/mL at 25 ℃ (lit.)
application(s)pharmaceutical (small molecule)
格式neat
储存温度2-8℃
SMILES string[H]C(=O)c1ccccc1OC
InChI1S/C8H8O2/c1-10-8-5-3-2-4-7(8)6-9/h2-6H,1H3
InChI keyPKZJLOCLABXVMC-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码10 - Combustible liquids
WGKWGK 2
闪点(F)244.4 °F - closed cup
闪点(C)118 ℃ - closed cup
109622Sigma-Aldrich2-Methoxybenzaldehyde98%200.7元/2 G;   501.51元/100 G;   1673.48元/500 G;   展开

产品说明

应用

在不对称 Henry 反应中,Cu (OAc) (2)-双(口恶唑啉)通过氢键作用可得到较好的对映体选择性 。
2-甲氧基苯甲醛已用于检查 杠柳 油及其活性成分对 腐食酪螨的杀螨活性

包装

2, 100, 500 g in glass bottle

生化/生理作用

天然存在的具有杀螨活性的芳香醛。可与食物中的 L-色氨酸缩合生成相应的强力抗氧化剂酚醛四氢-β-咔啉-3-羧酸。

基本信息

线性分子式CH3OC6H4CHO
分子量136.15
Beilstein606301
EC 号205-171-7
MDL编号MFCD00003308
PubChem化学物质编号24846928
NACRESNA.22

产品性质

质量水平100
测定98%
bp238 ℃ (lit.)
mp34-40 ℃ (lit.)
密度1.127 g/mL at 25 ℃ (lit.)
SMILES string[H]C(=O)c1ccccc1OC
InChI1S/C8H8O2/c1-10-8-5-3-2-4-7(8)6-9/h2-6H,1H3
InChI keyPKZJLOCLABXVMC-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 2
闪点(F)244.4 °F - closed cup
闪点(C)118 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
242823Fluorochem2-Methoxybenzaldehyde98%220元/1g;   330元/25g;   836元/100g;   2024元/500g;   展开

基本信息

CAS Number135-02-4
MDL NumberMFCD00003308
Boiling Point238℃
Melting Point34-40℃
Density1.127

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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