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CAS: 132388-59-1
分子式: C38H32N2O5
分子量: 596.68
熔点: 205℃
中文名称: 
Fmoc-N-三苯甲基-L-天冬酰胺
FMOC-N-β-TRITYL-L-天门冬酰胺
芴甲氧羰基-N-三苯甲基-L-天冬酰胺
英文名称: 
Nα-(9-Fluorenylmethoxycarbonyl)-Nγ-trityl-L-asparagine
Nalpha-[(9H-Fluoren-9-ylmethoxy)carbonyl]-Ngamma-trityl-L-asparagine
Nalpha-Fmoc-Ngamma-trityl-L-asparagine
fmoc-n-trityl-l-asparagine
fmoc-asn(trt)-oh
Fmoc-N-β-trityl-L-asparagine
推荐供应商
货号品牌产品名称规格包装、参考价格详情
F809668MACKLINFmoc-N-三苯甲基-L-天冬酰胺97%29元/5g;   124元/25g;   480元/100g;   2043元/500g;   展开
储存:2~8°C
折射率:-19 ° (C=1, DMF)
F0508TCINα-[(9H-Fluoren-9-ylmethoxy)carbonyl]-Nγ-trityl-L-asparagine>98.0%(T)(HPLC)155元/1G;   450元/5G;   1080元/25G;   展开

基本信息

纯度/分析方法>98.0%(T)(HPLC)
分子式/分子量C38H32N2O5 = 596.68
外观与形状(20℃)固体
Reaxys-RN4343823
PubChem物质ID87558122

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(HPLC)min. 98.0 area%
Purity(Neutralization titration)min. 98.0 %
Specific rotation [a]20/D-17.0 to -21.0 deg(C=1, DMF)
Solubility in N,N-DMFalmost transparency

物性(参考值)

比旋光度 [α]D-19° (C=1,DMF)
溶解性(可溶于)二甲基甲酰胺
185520J&KFmoc-N-trityl-L-asparagine98%81元/1G;   101元/5G;   217元/25G;   716元/100G;   展开

基本信息

分子式C38H32N2O5
分子量596.68
熔点201-204
比旋光度([α]20D)-16.5° to -12.5° (C=1, MeOH)
MDL编码MFCD00077049
Beilstein4343823
存储条件Store at 2-8℃

安全信息

防范说明P262
WGK2
TSCA
H59536Alfa AesarNalpha-Fmoc-Ngamma-trityl-L-asparagine97%1561元/5g;   2906元/25g;   展开

基本信息

MDL
MFCD00077049

分子式
C38H32N2O5

分子量
596.67

熔点
201-204°

形态
Powder

Beilstein
4343823

安全信息

TSCA

47672Sigma-AldrichFmoc-Asn(Trt)-OH≥97.0%637.74元/5 G;   1209.73元/25 G;   2051.56元/100 G;   15424.8元/1 KG;   展开

产品说明

一般描述

Fmoc-Asn(Trt)-OH has good solubility properties in most organic solvents, and its use has been shown to result in significantly purer peptides than other derivatives used for the introduction of Asn [1, 2]. Coupling can be performed by standard procedures. The trityl group is normally removed by 95% TFA in 1-3 hours, with no alkylation of Trp residues. When Asn(Trt) is the N-terminal residue, the reaction time may need to be extended to ensure complete deprotection [3].

应用

Fmoc-Asn(Trt)-OH has been used to synthesize peptides on cellulose membrane by SPOT method

包装

5, 25, 100 g in poly bottle
1 kg in poly bottle

基本信息

经验(实验)分子式C38H32N2O5
分子量596.67
Beilstein4343823
MDL编号MFCD00077049
eCl@ss32160406
PubChem化学物质编号57651076
NACRESNA.26

产品性质

质量水平100
测定≥97.0%
旋光性[α]20/D −15.0±1°, c = 1% in methanol
reaction suitabilityreaction type: Fmoc solid-phase peptide synthesis
mp201-204 ℃ (lit.)
application(s)peptide synthesis
官能团Fmoc
储存温度2-8℃
SMILES stringOC(=O)[C@H](CC(=O)NC(c1ccccc1)(c2ccccc2)c3ccccc3)NC(=O)OCC4c5ccccc5-c6ccccc46
InChI1S/C38H32N2O5/c41-35(40-38(26-14-4-1-5-15-26,27-16-6-2-7-17-27)28-18-8-3-9-19-28)24-34(36(42)43)39-37(44)45-25-33-31-22-12-10-20-29(31)30-21-11-13-23-32(30)33/h1-23,33-34H,24-25H2,(H,39,44)(H,40,41)(H,42,43)/t34-/m0/s1
InChI keyKJYAFJQCGPUXJY-UMSFTDKQSA-N

安全信息

象形图GHS09
危险声明H411
危险分类Aquatic Chronic 2
储存分类代码13 - Non Combustible Solids
WGKWGK 2
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
8.52044Sigma-AldrichFmoc-Asn(Trt)-OHN-α-Fmoc-N-ß-trityl-L-asparagine Novabiochem®636.66元/25 G;   1916.21元/100 G;   4084.74元/250 G;   7640元/500 G;   展开

产品说明

一般描述

Fmoc-Asn(Trt)-OH has good solubility properties in most organic solvents, and its use has been shown to result in significantly purer peptides than other derivatives used for the introduction of Asn [1, 2]. Coupling can be performed by standard procedures. The trityl group is normally removed by 95% TFA in 1-3 hours, with no alkylation of Trp residues. When Asn(Trt) is the N-terminal residue, the reaction time may need to be extended to ensure complete deprotection [3].

The product number for this product was previously 04-12-1089.

To obtain a certificate of analysis (CoA) of a lot that begins with the letter “A”, please select the option in the right hand menu “Request a COA for Lot#s starting with A”.

联系

Replaces: 04-12-1089

分析说明

Colour (visual): white to off white
Appearance of substance (visual): powder
Colour index (0,5 M in DMF): ≤ 150 Hazen
Identity (IR): passes test
Enantiomeric purity: ≥ 99.7 % (a/a)
Purity (HPLC): ≥ 99.0 % (a/a)
Fmoc-ß-Ala-OH (HPLC): ≤ 0.1 % (a/a)
Fmoc-ß-Ala-Asn (Trt)-OH (HPLC): ≤ 0.1 % (a/a)
Fmoc-Asn(Trt)-Asn(Trt)-OH (HPLC): ≤ 0.1 % (a/a)
Fmoc-Asn-OH (HPLC): ≤ 0.1 % (a/a)
Assay free amino acid (GC): ≤ 0.2 %
Purity (TLC(011A)): ≥ 98 %
Purity (TLC(0811)): ≥ 98 %
Solubility (25 mmole in 50 ml DMF): clearly soluble
Assay (acidimetric): ≥ 98.0 %
Water (K. F.): ≤ 2.0 %
Ethyl acetate (HS-GC): ≤ 0.5 %
Acetate (IC): ≤ 0.05 %
For TLC-Systems see our General Catalog

法律信息

Novabiochem is a registered trademark of Merck KGaA, Darmstadt, Germany

基本信息

经验(实验)分子式C38H32N2O5
分子量596.67
MDL编号MFCD00077049

产品性质

质量水平400
产品线Novabiochem®
测定≥98% (TLC)
≥98.0% (acidimetric)
≥99.0% (HPLC)
形式powder
效能>2000 mg/kg LD50, oral (Rat)
reaction suitabilityreaction type: Fmoc solid-phase peptide synthesis
manufacturer/tradenameNovabiochem®
mp210-220 ℃
溶解性 <0.00005 g/L
application(s)peptide synthesis
官能团Fmoc
储存温度15-25℃
InChI1S/C38H32N2O5/c41-35(40-38(26-14-4-1-5-15-26,27-16-6-2-7-17-27)28-18-8-3-9-19-28)24-34(36(42)43)39-37(44)45-25-33-31-22-12-10-20-29(31)30-21-11-13-23-32(30)33/h1-23,33-34H,24-25H2,(H,39,44)(H,40,41)(H,42,43)/p-1/t34-/m0/s1
InChI keyKJYAFJQCGPUXJY-UMSFTDKQSA-M

安全信息

象形图GHS09
危险声明H411
预防措施声明P273 - P391 - P501
危险分类Aquatic Chronic 2
储存分类代码11 - Combustible Solids
WGKWGK 2
闪点(F)Not applicable
闪点(C)Not applicable
M03352FluorochemFmoc-Asn(Trt)-OH98%220元/1g;   374元/10g;   726元/25g;   1870元/100g;   17270元/1kg;   展开

基本信息

CAS Number132388-59-1
MDL NumberMFCD00077049
Density1.271

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
H413: May cause long lasting harmful effects to aquatic life.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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