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CAS: 132-75-2
分子式: C12H9N
分子量: 167.21
沸点: 191-194℃
熔点: 33-35℃
中文名称: 
1-萘甲腈
萘甲腈
1-萘基乙睛
1-萘乙腈
α-萘乙腈
英文名称: 
1-Naphthylmethylcyanide
(1-naphthyl)-acetonitril
1-naphthaleneacetonitrile
alpha-(1-naphthyl)acetonitrile
alpha-naphthyl acetonitrile
1-naphthylacetonitrile
naphthalenyl-acetonitrile
性质描述: 白色结晶。熔点32-33℃,沸点162-164℃,191-194℃(2.4kPa),折光率(nD20)1.6192。不溶于水。
生产方法: 将695g 1-(氯甲基)萘、1500ml甲醇和475ml水、350g氰化钠的混合物沸腾回流,搅拌反应2h。蒸出1300ml甲醇,冷却,用水洗涤反应物至中性,得670-680g 1-萘乙腈。
用途: 有机合成中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
N837937MACKLIN1-萘乙腈97 %28元/5g;   42元/25g;   展开
储存:室温,干燥
状态:白色到橙色到绿色粉末到块状
N0366TCI1-Naphthylacetonitrile>98.0%(GC)290元/25G;   2520元/500G;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C12H9N = 167.21
外观与形状(20℃)固体
Reaxys-RN1101012
PubChem物质ID87573717
SDBS (AIST Spectral DB)7031
MDL编号MFCD00004041

技术规格

AppearanceWhite or Colorless to Yellow powder to lump to clear liquid
Purity(GC)min. 98.0 %

物性(参考值)

熔点29 ℃

安全信息

图形或危害标志
信号词危险
危险性说明H301 + H311 + H331 : 吞咽、皮肤接触或吸入中毒。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P361 + P364 : 立即脱掉所有沾染的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P310 + P330 : 如误吞咽:立即呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
P304 + P340 + P311 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P405 : 存放处须加锁。

相关法规

RTECS#AM1240000

运输信息

UN编号UN3439
类别6.1
包装类别 III
监管条件代码(*)
L06696Alfa Aesar1-Naphthylacetonitrile97%326元/5g;   935元/25g;   2975元/100g;   展开

基本信息

MDL
MFCD00004041

EINECS
205-078-1

分子式
C12H9N

分子量
167.21

熔点
33-35°

沸点
180-182°/9mm

闪点
>110°(230°F)

折射率
1.6192

Beilstein
1101012

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H312-H331-H315-H319-H335
Harmful if swallowed.Harmful in contact with skin.Toxic if inhaled.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
20/21/22-36/37/38
Harmful by inhalation, in contact with skin and if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

欧盟危险品标志

RTECS
AM1240000

TSCA

069119Fluorochem1-Naphthylacetonitrile97%220元/1g;   308元/25g;   1034元/100g;   4422元/500g;   展开

基本信息

CAS Number132-75-2
MDL NumberMFCD00004041
Melting Point29℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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