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CAS: 13192-04-6
分子式: C7H10O5
分子量: 174.15
沸点: 90℃(0.4
中文名称: 
α-酮戊二酸二甲酯
alpha-酮戊二酸二甲酯
英文名称: 
dimethyl 2-oxoglutarate
2-Ketoglutaric Acid Dimethyl Ester
2-Oxoglutaric Acid Dimethyl Ester
Dimethyl 2-Ketoglutarate
推荐供应商
货号品牌产品名称规格包装、参考价格详情
D858537MACKLIN2-氧化戊二酸二甲酯95%48元/1g;   152元/5g;   629元/25g;   2046元/100g;   展开
储存:室温,干燥,惰性气体存储
状态:无色到淡黄色液体
K0013TCIDimethyl 2-Oxoglutarate>95.0%(GC)1095元/5ML;   4150元/25ML;   展开

基本信息

纯度/分析方法>95.0%(GC)
分子式/分子量C7H10O5 = 174.15
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN1781665
PubChem物质ID87571950
SDBS (AIST Spectral DB)5737
MDL编号MFCD00048052

技术规格

AppearanceColorless to Light yellow to Light orange clear liquid
Purity(GC)min. 95.0 %

物性(参考值)

沸点117 ℃/3 mmHg
比重1.21
折射率1.44
349631Sigma-AldrichDimethyl 2-Oxoglutarate96%1505.93元/5 G;   展开

产品说明

一般描述

2-氧戊二酸二甲酯是在Krebs循环期间形成的关键中间体,并且是生物代谢途径中的重要氮转运子。2-氧戊二酸二甲酯的电化学行为已通过循环伏安法、方波伏安法和使用玻碳电极的差分脉冲伏安法进行了研究。

应用

2-氧代戊二酸二甲酯可以与双亲核物,如1,2-苯二胺、2-氨基苯酚和2-氨基苯硫醇,进行环缩合以形成新的杂环。
2-氧戊二酸二甲酯可用于合成构象受限的PNA(肽核酸)单体,该单体能够在三重基序中结合胸腺嘧啶。它可以通过与硝基苯乙烯的高度立体选择性Michael加成反应,合成4-芳基红藻氨酸类似物。

包装

5 g in glass bottle

基本信息

线性分子式CH3O2CCH2CH2COCO2CH3
分子量174.15
MDL编号MFCD00048052
PubChem化学物质编号24861693
NACRESNA.22

产品性质

质量水平100
测定96%
折射率n20/D 1.439 (lit.)
bp90-95 ℃/0.4 mmHg (lit.)
密度1.203 g/mL at 25 ℃ (lit.)
SMILES stringCOC(=O)CCC(=O)C(=O)OC
InChI1S/C7H10O5/c1-11-6(9)4-3-5(8)7(10)12-2/h3-4H2,1-2H3
InChI keyTXIXSLPEABAEHP-UHFFFAOYSA-N

安全信息

储存分类代码12 - Non Combustible Liquids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves
435702FluorochemDimethyl 2-oxopentanedioate95%220元/1g;   726元/5g;   2332元/25g;   8536元/100g;   展开

基本信息

CAS Number13192-04-6
MDL NumberMFCD00048052
Boiling Point117℃
Density1.21

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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