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CAS: 131880-16-5
分子式: C13H8BF7S
分子量: 340.07
熔点: 171-172°C
英文名称: 
5-(TRIFLUOROMETHYL)DIBENZOTHIOPHENIUM TETRAFLUOROBORATE
推荐供应商
货号品牌产品名称规格包装、参考价格详情
T829561MACKLIN5-(三氟甲基)二苯并噻吩四氟硼酸97%160元/200mg;   759元/1g;   展开
储存:2~8℃,干燥,密封
状态:淡黄色晶体粉末
236310J&K5-(Trifluoromethyl)dibenzothiophenium tetrafluoroborate97%1298元/1G;   5182元/5G;   展开

基本信息

分子式C13H8BF7S
分子量340.07
熔点162-164
MDL编码MFCD01073545

安全信息

防范说明P262
WGK3
483869Sigma-Aldrich5-(Trifluoromethyl)dibenzothiophenium tetrafluoroborate97%1199.94元/1 G;   展开

产品说明

应用

  • Pd(II)-催化的三氟甲基化
  • 铜催化的芳基硼酸三氟甲基化反应(以三甲吡啶为三氟甲基化试剂)
  • 芳烃的钯催化亲电邻位三氟甲基化

立体选择性制备用于
  • 铜催化末端烯烃三氟甲基化合成三氟甲基取代烯烃
  • 钯催化的 α-甲基丙烯分子内脱羧反应-三氟甲基 β-酮酸酯

包装

1 g in glass bottle

基本信息

经验(实验)分子式C13H8BF7S
分子量340.07
MDL编号MFCD01073545
PubChem化学物质编号24871922
NACRESNA.22

产品性质

质量水平100
测定97%
mp162-164 ℃ (lit.)
SMILES stringF[B-](F)(F)F.FC(F)(F)[S+]1c2ccccc2-c3ccccc13
InChI1S/C13H8F3S.BF4/c14-13(15,16)17-11-7-3-1-5-9(11)10-6-2-4-8-12(10)17;2-1(3,4)5/h1-8H;/q+1;-1
InChI keyVTVISWLINKWMQZ-UHFFFAOYSA-N

安全信息

储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
950572Amethyst5-(Trifluoromethyl)dibenzothiophenium tetrafluoroborate97%, 用于合成893元/1G;   3833元/5G;   展开

基本信息

分子式C13H8BF7S
分子量340.07
熔点162-164
MDL编码MFCD01073545

安全信息

防范说明P262
WGK3
227741Fluorochem5-(Trifluoromethyl)dibenzothiophenium tetrafluoroborate95%1936元/1g;   7722元/5g;   12386元/10g;   24772元/25g;   展开

基本信息

CAS Number131880-16-5
MDL NumberMFCD01073545

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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