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CAS: 131864-67-0
分子式: C17H23N3O2
分子量: 301.38
熔点: 154-156 °C(lit.)
英文名称: 
(R,R)-2,2'-(2,6-Pyridinediyl)bis(4-isopropyl-2-oxazoline)
2,6-bis((4R)-(+)-isopropyl-2-oxazolin-2-yl)pyridi
2,6-Bis[(4R)-(+)-isopropyl-2-oxazolin-2-yl]pyridine
(R,R)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine
推荐供应商
货号品牌产品名称规格包装、参考价格详情
B803100MACKLIN|R,R|-2,6-双(4-异丙基-2-恶唑啉-2-基)吡啶97%45元/250mg;   展开
储存:2~8°C
状态:白色粉末,晶体和/或块状
折射率:118 ° (C=1, CH2Cl2)
B2217TCI(R,R)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine>98.0%(GC)515元/250MG;   1310元/1G;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C17H23N3O2 = 301.39
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
Reaxys-RN15421598
PubChem物质ID87565072
MDL编号MFCD01321334

技术规格

AppearanceWhite to Light yellow powder to crystal
Purity(GC)min. 98.0 %
Optical purity(LC)min. 98.0 ee%
Melting point152.0 to 156.0 ℃

物性(参考值)

熔点154 ℃
比旋光度 [α]D118° (C=1,CH2Cl2)

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
353382J&K2,6-Bis[(4R)-(+)-isopropyl-2-oxazolin-2-yl]pyridine98%466元/250MG;   1055元/1G;   4209元/5G;   展开

基本信息

分子式C17H23N3O2
分子量301.38
熔点154-156
比旋光度([α]20D)+115° to +124° (C=0.7, Dichloromethane)
MDL编码MFCD01321334
Beilstein15421598
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
07-0306Strem(+)-2,6-Bis[(4R)-4-(i-propyl)-2-oxazolin-2-yl]pyridine98+%1709元/250mg;   5103元/1g;   展开

Technical Note:

1. L igand for enantioselective nitrone cycloaddition to a, ß-unsaturated 2-acyl imidazoles.

2.Highly efficient catalytic enantioselective Mannich reaction of malonates with N-tert-butoxycarbonyl imines .

References: 1.Org. L ett., 2006, 8 (15), 3351- 3354 2.Chem-Eur.J., 2013, 19, 10142.
07-1365Strem2,6-Bis[(4R)-isopropyl-2-oxazolin-2-yl]pyridine98%, (99% ee)1260元/1g;   展开
477494Sigma-Aldrich2,6-Bis[(4R)-(+)-isopropyl-2-oxazolin-2-yl]pyridine99%742.06元/250 MG;   2703.2元/1 G;   展开

产品说明

应用

不对称催化作用的 C2 对称配体。由于噁唑啉氮具有对各种金属的强亲合性,因此容易形成双齿配位络合物。

包装

250 mg in glass insert
1 g in glass bottle

基本信息

经验(实验)分子式C17H23N3O2
分子量301.38
MDL编号MFCD01321334
PubChem化学物质编号24871378
NACRESNA.22

产品性质

质量水平100
测定99%
旋光性[α]20/D +118°, c = 0.7 in methylene chloride
mp154-156 ℃ (lit.)
SMILES stringCC(C)[C@@H]1COC(=N1)c2cccc(n2)C3=N[C@@H](CO3)C(C)C
InChI1S/C17H23N3O2/c1-10(2)14-8-21-16(19-14)12-6-5-7-13(18-12)17-20-15(9-22-17)11(3)4/h5-7,10-11,14-15H,8-9H2,1-4H3/t14-,15-/m0/s1
InChI keyCSGQGLBCAHGJDR-GJZGRUSLSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
434646Fluorochem2,6-Bis((R)-4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine95%1188元/250mg;   2838元/1g;   10670元/5g;   展开

基本信息

CAS Number131864-67-0
MDL NumberMFCD01321334
Melting Point154℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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