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CAS: 131833-97-1
分子式: C17H30N2O2
分子量: 294.44
中文名称: 
(r,r)-(+)-2,2'-异亚丙基双(4-叔丁基-2-恶唑啉)
(r,r)-(+)-2,2'-(二甲基亚甲基)双(4-叔丁基-2-恶唑啉)
(r,r)-(+)-2,2-双(4-叔丁基-2-恶唑啉-2-基)丙烷
英文名称: 
(r,r)-(+)-2,2'-isopropylidenebis(4-tert-butyl-2-oxazoline)
(r,r)-(+)-2,2'-(dimethylmethylene)bis(4-tert-butyl-2-oxazoline)
(r,r)-(+)-2,2-bis(4-tert-butyl-2-oxazolin-2-yl)propane
推荐供应商
货号品牌产品名称规格包装、参考价格详情
R812116MACKLIN(R,R)-(+)-2,2'-异亚丙基双(4-叔丁基-2-恶唑啉)97%99元/100mg;   190元/250mg;   624元/1g;   展开
储存:室温
I0795TCI(R,R)-(+)-2,2'-Isopropylidenebis(4-tert-butyl-2-oxazoline)>98.0%(GC)1990元/100MG;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C17H30N2O2 = 294.44
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
Reaxys-RN4296340
PubChem物质ID125307736
MDL编号MFCD07368371

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 98.0 %
Melting point88.0 to 92.0 ℃
Specific rotation [a]20/D+112.0 to +123.0 deg(C=1, CHCl3)

物性(参考值)

熔点90 ℃
比旋光度 [α]D119° (C=1,CHCl3)
溶解性(可溶于)氯仿

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
297005J&K(R,R)-(+)-2,2'-Isopropylidenebis(4-tert-butyl-2-oxazoline)98%1806元/50MG;   3266元/250MG;   展开

基本信息

分子式C17H30N2O2
分子量294.44
MDL编码MFCD07368371

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
07-1058Strem2,2-Bis[(4R)-4-tert-butyl-2-oxazolin-2-yl]propane98%, (99% ee)1890元/100mg;   展开

Technical Notes :

1.Ligand for the enantioselective H-atom transfer Reactions to generate ß2-amino acids.

2.Ligand for the Cu-catalyzed asymmetric alkylation of ß-keto esters with xanthydrols .

3.Ligand used in Zn-catalyzed asymmetric hetero-Diels Alder reaction of trans-1 -methoxy-3-trimethylsilyloxy- buta-1,3-diene .

References:

1.Angew. Chem. Int. Ed. 2004, 43, 1235.

2.Adv. Synth. Catal. 2013, 355, 2815.

3.Eur. J. Org. Chem. 2020, 5388.

233762Fluorochem(4R,4'R)-2,2'-(Propane-2,2-diyl)bis(4-(tert-butyl)-4,5-dihydrooxazole)95%3410元/250mg;   8646元/1g;   29612元/5g;   展开

基本信息

CAS Number131833-97-1
MDL NumberMFCD07368371
Melting Point90℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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