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CAS: 131833-93-7
分子式: C17H30N2O2
分子量: 294.43
熔点: 84-89℃
英文名称: 
2,2'-Isopropylidenebis[(4S)-4-tert-butyl-2-oxazoline]
(S,S)-2,2'-Isopropylidene-bis(4-tert-butyl-2-oxazoline)
(S,S)-(-)-2,2'-Isopropylidenebis(4-tert-butyl-2-oxazoline)
(S,S)-(-)-2,2'-(Dimethylmethylene)bis(4-tert-butyl-2-oxazoline)
(S,S)-(-)-2,2-Bis(4-tert-butyl-2-oxazolin-2-yl)propane
(s,s)-2,2'-isopropylidene-bis(4-tert-butyl- 2-oxazoline)
推荐供应商
货号品牌产品名称规格包装、参考价格详情
I812554MACKLIN(S,S)-(-)-2,2'-异亚丙基双(4-叔丁基-2-恶唑啉)95%80元/100mg;   176元/250mg;   479元/1g;   展开
储存:室温
状态:白色到灰白色固体
折射率:-118 ° (C=1, CHCl3)
I0567TCI(S,S)-(-)-2,2'-Isopropylidenebis(4-tert-butyl-2-oxazoline)>97.0%(GC)590元/100MG;   2250元/1G;   展开

基本信息

纯度/分析方法>97.0%(GC)
分子式/分子量C17H30N2O2 = 294.44
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
Reaxys-RN4296341
PubChem物质ID87571911
MDL编号MFCD00192243

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 97.0 %
Melting point88.0 to 92.0 ℃
Specific rotation [a]20/D-112 to -123 deg(C=1, CHCl3)

物性(参考值)

熔点90 ℃
比旋光度 [α]D-118° (C=1,CHCl3)

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
211207J&K2,2'-Isopropylidenebis[(4S)-4-tert-butyl-2-oxazoline]98%301元/50MG;   1202元/250MG;   3208元/1G;   展开

基本信息

分子式C17H30N2O2
分子量294.44
熔点89-91
比旋光度([α]20D)-123° to -115° (C=1, CHCl3)
MDL编码MFCD00192243

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
406147Sigma-Aldrich2,2′-Isopropylidenebis[(4S)-4-tert-butyl-2-oxazoline]99%1256.7元/250 MG;   展开

产品说明

应用

不对称合成的手性催化剂。对映选择性催化反应的 C2 对称配体。由于噁唑啉氮具有对各种金属的强亲合性,因此容易形成双齿配位络合物。

包装

250 mg in glass bottle

基本信息

经验(实验)分子式C17H30N2O2
分子量294.43
MDL编号MFCD00192243
PubChem化学物质编号24865358
NACRESNA.22

产品性质

测定99%
旋光性[α]20/D −120°, c = 5 in chloroform
mp89-91 ℃ (lit.)
SMILES stringCC(C)(C)[C@H]1COC(=N1)C(C)(C)C2=N[C@H](CO2)C(C)(C)C
InChI1S/C17H30N2O2/c1-15(2,3)11-9-20-13(18-11)17(7,8)14-19-12(10-21-14)16(4,5)6/h11-12H,9-10H2,1-8H3/t11-,12-/m1/s1
InChI keyDPMGLJUMNRDNMX-VXGBXAGGSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
972653Amethyst2,2'-Isopropylidenebis[(4S)-4-tert-butyl-2-oxazoline]98%, 用于合成383元/250MG;   1239元/1G;   3658元/5G;   展开

基本信息

分子式C17H30N2O2
分子量294.44
熔点89-91
比旋光度([α]20D)-123° to -115° (C=1, CHCl3)
MDL编码MFCD00192243

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
046836Fluorochem(S,S)-(-)-2,2'-Isopropylidenebis(4-tert-butyl-2-oxazoline)97%1408元/250mg;   2684元/1g;   10626元/5g;   15950元/10g;   展开

基本信息

CAS Number131833-93-7
MDL NumberMFCD00192243
Melting Point88-92℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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