CAS 1316861-19-4; (2<i>r</i>)-2-phenyl-3,4-dihydro-2<i>h</i>-pyrimido[2,1-b][1,3]benzothiazole

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CAS:

1316861-19-4

分子式:

C₁₆H₁₄N₂S

分子量:

266.36

熔点:

145-147 °C

英文名称:

(2r)-2-phenyl-3,4-dihydro-2h-pyrimido[2,1-b][1,3]benzothiazole

(r)-homobenzotetramisole

(r)-2-phenyl-3,4-dihydro-2h-benzo[4,5]thiazolo[3,2-a]pyrimidine

birman (r)-hbtm

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货号

品牌

产品名称

规格

包装、参考价格

详情

R968572

MACKLIN

(R)-2-苯基-3,4-二氢-2H-苯并[4,5]噻唑并[3,2-a]嘧啶

98%

599元/100mg; 896元/250mg; 2644元/1g;

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储存：2-8°C, 惰性气体
状态：固体

901233

Sigma-Aldrich

(2R)-2-Phenyl-3,4-dihydro-2H-pyrimido[2,1-b][1,3]benzothiazole

≥95%

1781.35元/100 MG;

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产品说明

应用

This chiral isothiourea homobenzotetramisole ((R)-HBTM) developed by the Birman lab is an organocatalyst that has been used for kinetic resolution, determination of absolute configuration, and nucleophile-catalysed, Michael–aldol-b-lactonization (NCMAL). This same product was previously listed as L511730, and the complementary (S)-HBTM organocatalyst (900542) is also available.

其他说明

Technology Spotlight: Homobenzotetramisole (HBTM): A General Organocatalyst for Asymmetric Acylations

[1] Determination of the Absolute Configuration β-Chiral Primary Alcohols Using the Competing Enantioselective Conversion Method

[2] Asymmetric Catalytic Synthesis of Thiochromenes via an Acyl Transfer-Initiated Cascade

[3] Rapid assembly of complex cyclopentanes employing chiral, α, β-unsaturated acylammonium intermediates

[4] Determination of Absolute Configuration Using Kinetic Resolution Catalysts

[5] Kinetic Resolution of Secondary Alcohols Using Amidine-Based Catalysts

基本信息

经验(实验)分子式	C₁₆H₁₄N₂S
分子量	266.36
MDL编号	MFCD26793803

产品性质

质量水平	100
测定	≥95%
形式	powder or chunks
mp	145-147 ℃
储存温度	2-8℃
SMILES string	C12=CC=CC=C1SC3=N[C@@H](C4=CC=CC=C4)CCN23
InChI	1S/C16H14N2S/c1-2-6-12(7-3-1)13-10-11-18-14-8-4-5-9-15(14)19-16(18)17-13/h1-9,13H,10-11H2/t13-/m1/s1
InChI key	ZMYZJAQMQBHNLH-CYBMUJFWSA-N

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

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