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CAS: 1185-57-5
分子式: C12H22FeN3O14
分子量: 488.16
中文名称: 
棕色柠檬酸铁铵
枸椽酸铁铵(棕色)
棕色枸椽酸铁铵
2-羟基-1,2,3-丙三羧酸铁(III)铵盐
枸橼酸铁铵
柠檬酸铁铵
枸椽酸铁铵
柠檬酸铁铵(棕色)
英文名称: 
Ammonium iron(III)citrate
Ammonium iron(III)citrate,brown
Fraser Supplement
Amonium Iron(III)Citrate Supplement
1,2,3-Propanetricarboxylic acid,2-hydroxy-,ammonium iron(3+)salt
Ammonium iron citrate
Iron and ammonium cit-rate
Ferric ammonium citrae
Ammonium ferric citrate brown
1,2,3-Propanetricarboxylic acid, 2-hydroxy-, ammonium iron(3+) salt
Ammonium ferric citrate
citric acid, ammonium iron(3+) salt
2,3-propanetricarboxylic acid, 2-hydroxy- ammonium iron(3+) salt
2,3-propanetricarboxylic acid, 2-hydroxy- ammonium iron(3++) salt
ammonium iron(iii) citrate
fac
ferric ammonium citrate
iron ammonium citrate
iron(iii) ammonium citrate
Ammonium ferric citrate,brown
ferricammoniumcitrate
展开更多英文名
性质描述: 该品为赤褐色透明的鳞片状或粒状结晶。能溶于水,不溶于乙醇和醚。无臭,具有咸味和弱铁锈味。在湿空气中可潮解,水溶液呈弱碱性的反应。柠檬酸铁铵是柠檬酸铁FeC6H5O7的柠檬酸铵(NH4)3C6H5O7的复盐,其组成因合成条件不同而异没有确切的化学式。棕色鳞片状的晶体含铁量较高,达18.5%.绿色鳞片状的合铁量较低。
生产方法: 把氢氧化铁溶解于柠檬酸中,用氨水和,再经干燥而得。(1)氢氧化铁的制备 将硫酸亚铁加入水中,在搅拌下徐徐加入硫酸,再加入氯酸钠水溶液。然后剧烈搅拌,温度上升至80℃以上,再加入氯酸钠。搅拌直至反应终止(用铁氰化钾检查不呈亚铁反应),得硫酸铁溶液。将此溶液加入反应罐内,加氢氧化钠溶液,剧烈搅拌,反应温度为80-90℃,反应液由粘稠变稀薄时,加水洗涤至硫酸根和氯根符合要求止。沥干得氢氧化铁。(2)柠檬酸铁铵制备 将柠檬酸、氢氧化铁和水加入反应罐内,搅拌,温度控制在95℃以上,保温1h。然后冷至50℃,搅拌下通氨。静置48h以上。取上清液过滤,滤液浓缩成膏状,于80℃干燥得柠檬酸铁铵。对硫酸亚铁的总收率为73-75%。
用途: 棕色品用作补血药,以治疗缺铁性贫血;可作为食品添加剂,按日本《食品添加物公定书》规定,含铁量为16.5%-21.2%。棕色品和绿色品都是化学敏感物质,绿色品较棕色品更易感光。涂有绿色柠檬酸铁铵和赤血盐(铁氰化钾)的纸称为蓝色晒图纸。在曝光时,柠檬酸盐内的三价铁原为二价,遇水即产生腾氏蓝,故受光部分变为蓝,不受光部分仍为白色,可得蓝底白线图样。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
A800010MACKLIN柠檬酸铁铵试剂级114元/500g;   455元/2.5kg;   866元/5kg;   展开
储存:室温,避光
状态:棕色粉末

388571J&KFerric ammonium citrate17.5 - 22.5% 铁480元/250G;   649元/1KG;   展开

基本信息

分子式C6H11FeNO7
分子量261.97
MDL编码MFCD00013099
Merck14,4017
EINECS 编号214-686-6

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
RTECSGE7540000
TSCA
A11199Alfa AesarAmmonium iron(III) citratebrown303元/250g;   944元/1000g;   4328元/5000g;   展开

应用
Ammonium iron(III) citrate, brown is used in medicine, in making blueprints, and as a feed additive. It is also used as an iron supplement and food enhancer.

备注
Hygroscopic. Desiccate at room temperature. Store in the dark. Store under inert gas.

基本信息

MDL
MFCD00013099

EINECS
214-686-6

灵敏度
Hygroscopic. Light Sensitive. Ambient temperatures.

形态
Granular

溶解性
Soluble in water.1200 g/L (20°C)

Merck
14,4017

安全信息

RTECS
GE7540000

TSCA

C21184Alfa AesarAmmonium iron(III) citrate16.5 to 18.5% Fe1243元/250g;   1619元/1kg;   3726元/2.5kg;   14587元/10kg;   展开

基本信息

Ref#
21184

MDL
13099

分子式
C6 H11 Fe N O7

分子量
265

形态
Granular

I72-500Alfa AesarFERRIC AMMON CITRTE PURIF 500G696元/500g;   展开

基本信息

Ref#
F53176

1.00092MilliporeFRASER Listeria Ammonium iron (III) Supplementfor Listeria spp., pkg of 10 vials, for the preparation of Half FRASER (Demi FRASER) Broth (Base) or FRASER Broth (Base)799.06元/10 VIAL;   展开

产品说明

一般描述

For preparation of FRASER broth, two different supplements are needed: FRASER Listeria Selective Supplement and FRASER Listeria Ammonium Iron (III) Supplement. The ammonium iron (III) citrate promotes the growth of the Listeria spp., and together with esculin (a component of the FRASER broth base), permits the β-D-glucosidase detection in Listeria spp.

应用

FRASER Listeria Ammonium iron (III) Supplement is an additive for the preparation of Half FRASER (Demi FRASER) Broth (Base) or FRASER Broth (Base) for the enrichment of Listeria spp.

联系

Replaces: 1000920017

分析说明

Growth promotion test according to ISO 11133
Mixed inoculum of Listeria, E.coli and E.faecalis
Additionaly monoculture of E.coli and E.faecalis
Pre-enrichment in Half Fraser Broth, afterwards enrichment in Fraser Broth
Confirmation on ALOA®-Medium resp. Tryptic soy agar
Inoculum on reference medium
- Listeria monocytogenes ATCC 19111 (WDCM 00020):
10 - 100
- Listeria monocytogenes ATCC 13932 (WDCM 00021): 10 - 100
- Escherichia coli ATCC 25922 (WDCM 00013): ≥ 1000
- Escherichia coli ATCC 8739 (WDCM 00012): ≥ 1000
- Enterococcus faecalis ATCC 19433 (WDCM 00009): ≥ 1000
- Enterococcus faecalis ATCC 29212 (WDCM 00087): ≥ 1000
Blacking
- Listeria monocytogenes ATCC 19111 (WDCM 00020):
+
- Listeria monocytogenes ATCC 13932 (WDCM 00021): +
- Escherichia coli ATCC 25922 (WDCM 00013): -
- Escherichia coli ATCC 8739 (WDCM 00012): -
- Enterococcus faecalis ATCC 19433 (WDCM 00009): -
- Enterococcus faecalis ATCC 29212 (WDCM 00087): -
Growth on ALOA medium
- Listeria monocytogenes ATCC 19111 (WDCM 00020):
>10 CFU
- Listeria monocytogenes ATCC 13932 (WDCM 00021): >10 CFU
Colonies
- Listeria monocytogenes ATCC 19111 (WDCM 00020):
bluegreen with non transparent zone
- Listeria monocytogenes ATCC 13932 (WDCM 00021): bluegreen with non transparent zone
Growth on Tryptic soy agar
- Escherichia coli ATCC 25922 (WDCM 00013):
no growth
- Escherichia coli ATCC 8739 (WDCM 00012): no growth
- Enterococcus faecalis ATCC 29212 (WDCM 00087): <100 CFU
- Enterococcus faecalis ATCC 19433 (WDCM 00009): <100 CFU
Incubation:
Half Fraser Broth: 24 hours at 30°C, aerobic
Fraser Broth: 48 hours at 37°C, aerobic
Confirmation on ALOA-Medium: 48 hours at 37°C, aerobic
Confirmation on Tryptic soy agar: 24 hours at 35°C, aerobic

法律信息

ALOA is a registered trademark of Biolife Italiana S.r.l.
GRANUCULT is a registered trademark of Merck KGaA, Darmstadt, Germany

基本信息

经验(实验)分子式C6H8O7 · xFe · xH3N
MDL编号MFCD03099410
EC索引号214-686-6

产品性质

质量水平200
agencyISO 11290
ISO
形式lyophilized powder
效能>2000 mg/kg LD50, oral (Rat)
组成Ammonium iron (III) citrate, 250 mg per vial
包装pkg of 10 vials
technique(s)microbiological culture: suitable
pH值(酸碱度)6-8 (20 ℃, 100 g/L in H2O)
溶解性 1200 g/L
application(s)food and beverages
microbiology
pathogen testing
相容性GranuCult® FRASER Broth (Base) (1.10398)
GranuCult® Half FRASER (Demi FRASER) Broth (Base) (1.00025)
储存温度15-25℃
适用性Listeria spp.
InChI1S/C6H8O7.Fe.H3N/c7-3(8)1-6(13,5(11)12)2-4(9)10;;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);;1H3/q;+3;/p-3
InChI keyFRHBOQMZUOWXQL-UHFFFAOYSA-K

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
90836MilliporeFraser Supplementsuitable for microbiology1015.51元/10 VIALS;   展开

产品说明

一般描述

ISO 委员会建议将本品用于食物、动物饲料等物质中的单核细胞增多性李斯特菌的选择性分离和计数。

应用

for selective isolation and enumeration of Listeria monocytogenes from food, animal feeds etc.

组分

(每瓶,足够用于 500mL 培养基)
柠檬酸铁铵 250mg

基本信息

EC 号214-686-6
MDL编号MFCD03099410

产品性质

质量水平100
无菌性sterile
形式powder
保质期limited shelf life, expiry date on the label
application(s)environmental
food and beverages
pathogen testing
microbiology
适用性Listeria spp.
InChI1S/C6H8O7.Fe.H3N/c7-3(8)1-6(13,5(11)12)2-4(9)10;;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);;1H3/q;+3;/p-3
InChI keyFRHBOQMZUOWXQL-UHFFFAOYSA-K

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
RES20400-A7SAFCFerric ammonium citrate4712.1元/1 kg;   16867.5元/5 kg;   展开

产品说明

一般描述

如需获取此产品的相关文档,请联系客户支持并选择“产品文档”。请注意,需要签署保密协议才能获取该产品的相关文档。

包装

产品具有以下包装规格:
RES20400-A702X: 1 kg容器
RES20400-A703X: 5 kg容器

基本信息

线性分子式C6H8O7 ·xFe3+ · yNH3
EC 号214-686-6
NACRESNA.21

产品性质

生物来源synthetic
形式powder
杂质 Trace metals; tested
适用性suitable for manufacturing use
SMILES stringN.OC12CC(=O)O[Fe](OC(=O)C1)OC(=O)C2
InChI1S/C6H8O7.Fe.H3N/c7-3(8)1-6(13,5(11)12)2-4(9)10;;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);;1H3/q;+3;/p-3
InChI keyFRHBOQMZUOWXQL-UHFFFAOYSA-K

安全信息

储存分类代码11 - Combustible Solids
闪点(F)Not applicable
闪点(C)Not applicable
F5879Sigma-AldrichAmmonium iron(III) citratereagent grade, powder867.89元/100 G;   1912.32元/500 G;   展开

基本信息

线性分子式C6H8O7 ·xFe3+ · yNH3
EC 号214-686-6
eCl@ss38190508
PubChem化学物质编号24894895
NACRESNA.55

产品性质

质量水平200
等级reagent grade
形式powder
组成Iron, 16.5-18.5%
痕量阳离子Fe: 16.5-18.5%
SMILES stringN.OC12CC(=O)O[Fe](OC(=O)C1)OC(=O)C2
InChI1S/C6H8O7.Fe.H3N/c7-3(8)1-6(13,5(11)12)2-4(9)10;;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);;1H3/q;+3;/p-3
InChI keyFRHBOQMZUOWXQL-UHFFFAOYSA-K

安全信息

储存分类代码11 - Combustible Solids
WGKWGK 1
492548FluorochemAmmonium iron(III) citrate16.5-18.5% (Fe content)440元/250g;   1012元/1kg;   4620元/5kg;   展开

基本信息

CAS Number1185-57-5
MDL NumberMFCD00013099

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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