Technical Notes:

1.Used for Pd-catalyzed asymmetric arylation, vinylation, and Allenylation of tert-cyclobutanols via

enantioselective c-c Bond cleavage.

2.Used for synthesis of chiral chromans through the Pd-catalyzed asymmetric allylic alkylation (AAA).

4.Catalyst for double N-arylation of primary amines to synthesize multisubstituted carbazoles from 2,2'- biphenylylene ditriflates .

4. Paladium catalyst for regio- and enantioselective allylic alkylation of ketones through allyl enol carbonates .

5.Used for Pd-catalyzed enantioselective C-3 allylation of 3-substituted-1H-indoles using trialkylboranes.

6.Used for enantioselective construction of spirocyclic oxindolic cyclopentanes by Pd-catalyzed

trimethylenemethane-3 +2-cycloaddition.

7. Usewd for Pd-catalyzed insertion of a diazoesters into vinyl halides to generate a,ß-unsaturated Y amino

Esters.

8.Pd catalyst for decarboxylative asymmetric allylic alkylation of enol carbonates .

9.Palladium catalyst for asymmetric addition of oxindoles and allenes

10. Catalyst for diastereo- and enantioselective formal 3+ 2-cycloaddition between substituted

vinylcyclopropanes and electron-deficient olefins.

11. Used for Pd-catalyzed asymmetric decarboxylative cycloaddition of vinylethylene carbonates with Michael

sacceptors.

12. Catalyst for enantioselective 6+4 cycloaddition of vinyl oxetanes with azadienes to access ten-membered

heterocycles.