Technical Notes:

1. Introduced as an easier to handle Pd/P(t-Bu)3-based catalyst for the Negishi cross-coupling of aryl/vinyl chlorides.

2.A versatile catalyst for the cross- coupling of aryl and vinyl chlorides.

3.Catalyst for the amination of aryl chlorides and bromides using aqueous hydroxide bases.

4.UsefuI catalyst for the cross-coupling of heteroaromatic carboxylic acids.

5.Pd-catalyzed Newnan-Kwart rearrangement of o-aryl thiocarbamates.

6.Cross-coupling of silanolates and halides.

7.Elimination/isomerization of enol triflates derived from ß-ketoesters.

References:

1. J. Am. Chem. Soc., 2001, 123, 2719.

2. Handbook of Palladium Catalyzed Organic Reactions, 1997.

3.Palladium Reagents and Catalysis, 1995 (Tsuji).

4.J. Am. Chem. Soc.,2002，124，6343

5.J. Am. Chem. Soc., 2001, 123, 2719.

6.J. Org. Chem., 2002, 67, 6479.

7.J. Am. Chem. Soc., 2006, 128, 1 1350.

8.Angew. Chem. Int. Ed., 2009, 48, 7612.

9.J. Am. Chem. Soc., 2009, 131, 3104.

10. Angew. Chem. Int. Ed., 2011, 50, 6128.