二乙酸基{（S）-（+）-5,5'-双[二（3,5-二-叔-丁基-4-甲氧基苯基）膦基]-4,4'-双-1,3-苯并间二氧杂环戊烯}钌（II）

Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)?[(S)-dtbm-segphos?]

货号:J3444-0181

品牌:Strem

CAS NO:1025476-84-9

分子式:C??H???O??P?Ru

分子量:1398.69

仅供研发或工业应用，不可直接用于食品、药品、临床诊断或治疗。

产品介绍

Technical Notes:

1. Biaryl bisphosphine ligand with narrow dihedral angle. The DM-S EGPHOS ligand, as the ruthenium complex, gives superior

ena ntioselectivity and dias te re oselectivity in the asymmetric hydrogenation of a-subs tituted- ß-ke toesters. See 1 5-0066

2.Ruthenium catalyzed enantioselective synthesis of ß amino acids by hyd rogenation

3.Ruthenium catalyzed asymmetric hydrogenation of 3 quinuclidinone. See 44-0098 for Ru catalyst.

References:

1. WIPO Pat. WO20050284 19.

2. u.S. Pat. App.2006047122.

应用分类

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