Technical Notes:

1Chiral ligand for ruthenium- catalyzed asymmetric hydrogenation of aromatic ketones.

2.Chiral ligand for iridium- catalyzed asymmetric hydrogenation of quinolines .

3.Chiral ligand for copper- catalyzed as ymmetric hydrosilylation of ketones.

4.Synthesis of new chiral 2-functionized-1 ,2,3,4-tetrahydroquinoline derivatives via as ymmetric hydrogenation of s ubstitutedquinolines

5.Rhodium-biphosphine-catalyzed as ymmetric, intermolecular hydroheteroarylation of a-substituted acrylate derivatives.

References:

1J. Organomet. Chem..2006, 691.2332.

2.Tetrahedron Asym.2007. 18, 2625.

3.Chem. Eur. J.. 2009. 15, 5888.

4.Tetrahedron, 2013, 69, 9322.

5. J. Am. Chem. Soc.. 2015, 137. 508.