(11bR)-8,9,10,11,12,13,14,15-八氢-4-羟基-2,6-二-1-萘基-4-氧化物二萘并[2,1-d:1',2'-f][1,3,2]二噁磷杂庚英

(11bR)-8,9,10,11,12,13,14,15-八氢-4-羟基-2,6-二-1-萘基-4-氧化物二萘并[2,1-d:1',2'-f][1,3,2]二噁磷杂庚英，95%

(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-di-1-naphthalenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 95%, (98.5% ee)

货号:J3415-1383

品牌:Strem

纯度:95%

CAS NO:1242066-20-1

分子式:C??H??O?P

分子量:608.7

包装	价格
25mg	2177元	留言咨询
100mg	6463元	留言咨询

仅供研发或工业应用，不可直接用于食品、药品、临床诊断或治疗。

产品介绍

Technical Notes:

1.Friedel-Crafts Alkylation: Chiral phosphoric acid catalyzed F riedel-Crafts alkylation of indoles with 3,3,3- trifluoropyruvate gave the corresponding adducts in excellent yields with high enantioselectivities.

2.Pinacol Rearrangement: It has been found that indolyl diols can be treated with chiral phosphoric acids to effect a regio- and enantiose lective pinacol rearrangement with high efficiency.

References:

1.Asian J. Chem.. 2010, 5, 470-472.

2. Angew. Chem. Int. Ed., 2010, 49, 9734-9736.

应用分类

有机化学 > 催化剂和配体 > 配体 > 膦配体 > 其他膦配体

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