(11bR)-2,6-双[3,5-双(三氟甲基)苯基]-8,9,10,11,12,13,14,15-八氢-4-羟基-4-氧化物-二萘并[2-,1-d:1',2'-f][1,3,2]二氧磷杂七环

(11bR)-2,6-双[3,5-双(三氟甲基)苯基]-8,9,10,11,12,13,14,15-八氢-4-羟基-4-氧化物-二萘并[2-,1-d:1',2'-f][1,3,2]二氧磷杂七环，98%, (99% ee)

(11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-8,9,10,11,12,13,14,15-octahydro-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)

货号:J3415-1376

品牌:Strem

纯度:98%, (99% ee)

CAS NO:1011465-24-9

分子式:C??H??F??O?P

分子量:780.5

包装	价格
25mg	2160元	留言咨询
100mg	6413元	留言咨询

仅供研发或工业应用，不可直接用于食品、药品、临床诊断或治疗。

产品介绍

Technical Notes:

1. The preparation of binaphthol monophosphoric acid derivatives.

2.Sigmatropic Rearrangements: Used in the organocatalytic aryl-aryl bond-forming process for the regio- and atroposelective synthesis of 2,2'-diamino-1,1'-binaphthalenes (BINAMs).In the presence of catalytic amounts of axially chiral phosphoric acids, achiral N,N'-binaphthyl hydrazines undergo a facile 3,3-

sigmatropic rearrangement to afford enantiomerically enriched BINAM derivatives in good to excellent yield.

References:

1: JP4725757E81038877 u86274745,12000-3-21.

应用分类

有机化学 > 催化剂和配体 > 配体 > 膦配体 > 其他膦配体

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