(S)-(-)-2,2'-双[二(3,5-二甲苯基)磷]-1,1'-联萘

(S)-(-)-2,2'-双[二(3,5-二甲苯基)磷]-1,1'-联萘，98%

(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl, 98% (S)-(-)-XylBINAP

货号:J3415-0477

品牌:Strem

纯度:98%

CAS NO:135139-00-3

分子式:C??H??P

分子量:734.90

仅供研发或工业应用，不可直接用于食品、药品、临床诊断或治疗。

产品介绍

Technical Notes:

1.See 15-0150.

2.See 15-0476.

3.Ligand used in copper- catalyzed as ymmetric Mannich-type reactions of N- acylimino esters.

4.Ligand used in the enantios elective fluorination of oxindoles .

5.Ligand used in 2+2+2 cycloaddition of tetraynes and hexaynes.

6. L igand used in the as ymmetric reduction of ketone via ruth enium-catalyzed transfer hydrogenation. 7.Asymmetric hydroboration of uns

aturated imines .

References:

1. J. Am. Chem. Soc., 2003, 125, 2507.

2.J. Am. ( hem. Soc., 2005, 127, 10164.

3.Tetrahedron, 2008, 64, 82 1.

4.J. Am. Chem. Soc., 2011, 133, 10696.

5.Org. L ett., 2013, 15, 4810.

应用分类

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