(4S,4'S)-2,2'-(1,3-双[4-叔丁基苯基)丙烷-2,2-二基]双(4-苯基-4,5-二氢恶唑)

(4S,4'S)-2,2'-(1,3-Bis[4-(t-butyl)phenyl)propane-2,2-diyl]bis(4-phenyl-4,5-dihydrooxazole) (S)-BTBBPh-SaBOX

货号:J3407-1235

品牌:Strem

CAS NO:1428328-51-1

分子式:C??H??N?O

分子量:598.81

仅供研发或工业应用，不可直接用于食品、药品、临床诊断或治疗。

产品介绍

Technical Note:

1. A chiral cage like copper (I) catalyst for the highly enantioselective synthesis of 1.1- cyclopropane diesters.

2.Direct catalytic asymmetric synthesis of ß-hydroxy acids from malonic acid.

3. Asymmetric intramolecular desymmetrization of meso-a,a -diazido alcohols with aryldiazoacetates.

4. Catalytic asymmetric [3+ 1]-cycloaddition re action of ylides with electrophilic metallo-enolcarbene

intermediates.

References:

1.Angew. Chem. Int. Ed., 2012, 51, 11620. 2.

2.Org. Lett., 2015, 17, 5962.

3.Org. L ett., 2016, 18, 1984.

4. Angew. Chem. int. Ed., 2017, 56, 7479.

应用分类

推荐产品