(S)-2-[[(1R,2R)-2-氨基环己基]硫脲基]-N-苄基-N,3,3-三甲基丁酰胺

(S)-2-[[(1R,2R)-2-氨基环己基]硫脲基]-N-苄基-N,3,3-三甲基丁酰胺，98%, (99% ee)

(2S)-2-[[[[(1R,2R)-2-Aminocyclohexyl]amino]thioxomethyl]amino]-N,3,3-trimethyl-N-(phenylmethyl)butanamide, 98%, (99% ee)

货号:J3407-0956

品牌:Strem

纯度:98%, (99% ee)

CAS NO:479423-21-7

分子式:C??H??N?OS

分子量:390.60

包装	价格
50mg	2784元	留言咨询

仅供研发或工业应用，不可直接用于食品、药品、临床诊断或治疗。

产品介绍

Technical Notes:

1.Conjugate Addition: Primary amine -thiourea derivative is an active and highly enantioselective catalyst for the conjugate addition of ketones to nitroalkenes.

2.Michael Addition: The asymmetric Michael addition of dioxindoles to ß-substituted nitroalkenes is reported. The bifunctional primary amine-thiourea, by means of a non-covalent-based mode of catalysis, secures

direct access to 3-substituted 3-hydroxyoxindole derivatives with high stereocontrol.

References:

1. J. Am. Chem. Soc., 2006, 128, 7170-7171.

2. Chem. Commun., 2012, 48, 3336-3338.

应用分类

有机化学 > 催化剂和配体 > 有机分子催化剂 > 其他有机分子催化剂

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