Technical Notes

1. Used for branch-selective reductive c-c coupling of allenes to paraformaldehyde and higher aldehydes via Ru-catalyzed transfer hydrogenation

2.Used in anti-aminoallylation of aldehydes via Ru-catalyzed transfer hyd rogenative coupling of sulfonamidoallenes

3.Organometallic precursor used in the electron beam-induced deposition (EBID) 3-4, 7

4.Organometallic precursor used in photochemical chemical vapour deposition (CVD) of ruthenium on

functionalized self-assembled monolayers 5-6

References:

1.Org. L ett., 2008, 10, 2705

2.J. Am. Chem. Soc. 2009, 131, 5054

3.J. Phys. Chem. c 2015, 1 19, 15349

4. Phys. Chem. Chem. Phys.. 2017, 19, 13264