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CAS: 51010-74-3
分子式: C4H8F3NOS
分子量: 175.16
沸点: 41-42℃(0
英文名称: 
morpholinosulfur trifluoride
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货号品牌产品名称规格包装、参考价格详情
M862151MACKLIN三氟硫基吗啉93%(T)36元/1g;   85元/5g;   330元/25g;   1150元/100g;   4699元/500g;   展开
储存:2-8°C,惰性气体存储
状态:浅黄色液体
M1573TCIMorpholinosulfur Trifluoride>93.0%(T)370元/1G;   1280元/5G;   展开

基本信息

纯度/分析方法>93.0%(T)
分子式/分子量C4H8F3NOS = 175.17
外观与形状(20℃)液体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解),加热
Reaxys-RN606224
PubChem物质ID87561269
MDL编号MFCD00037057

技术规格

AppearanceColorless to Light orange to Yellow clear liquid
Purity(Neutralization titration)min. 93.0 %

物性(参考值)

沸点42 ℃/0.5 mmHg
闪点76 ℃
折射率1.45

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
H227 : 可燃液体。
H290 : 可能腐蚀金属。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P234 : 只能在原容器中存放。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P390 : 吸收溢出物,防止材料损坏。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P403 + P235 : 存放在通风良好的地方。保持低温。
P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。
P405 : 存放处须加锁。

运输信息

UN编号UN3265
类别8
包装类别 II
监管条件代码(*)
L19751Alfa Aesar4-Morpholinylsulfur trifluoride95%847元/1g;   2703元/5g;   10712元/25g;   展开

应用
4-Morpholinylsulfur trifluoride is incorporated in the fluoronation of trihexanols. It is used as a nucleophilic fluorinating agent with greater thermal stability. It is also used in the preparation of proline analogs and in the preparation of difluoropiperidines.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with bases and oxidizing and bases. Store under dry inert gas. It is sensitive to moisture.

基本信息

MDL
MFCD00037057

分子式
C4H8F3NOS

分子量
175.17

沸点
41-42°/0.5mm

闪点
76°(168°F)

密度
1.436

折射率
1.4545

灵敏度
Store at -20°C. Moisture Sensitive. May form a Precipitate.

形态
Liquid

溶解性
Reacts with water.

Beilstein
606224

GHS危害和防范说明

GHS符号

Hazard Statements
H227-H314-H318
Combustible liquid.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P280-P305+P351+P338-P309-P310-P402
Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed or if you feel unwell:Immediately call a POISON CENTER or doctor/physician.Store in a dry place.

安全信息

危险等级
8

包装组
II

危险类别
14-34
Reacts violently with water.Causes burns.

安全等级
8-26-36/37/39-45
Keep container dry.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA

002337FluorochemMorpholinosulfur Trifluoride95%594元/1g;   2156元/5g;   展开

基本信息

CAS Number51010-74-3
MDL NumberMFCD00037057
Boiling Point41-42℃
Density1.436

安全信息

图形或危害标志
危险性说明 H290: May be corrosive to metals.
H314: Causes severe skin burns and eye damage.
防范说明 P234: Keep only in original container.
P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P390: Absorb spillage to prevent material damage.
P405: Store locked up.
P406: Store in corrosive resistant/ container with a resistant inner liner.
P501: Dispose of contents/container to local regulations.
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